Perfume Delivery System

ABSTRACT

Described herein are perfume delivery systems, in particular, a delivery system including a biodegradable carrier and a perfume formulation, as well as and a perfuming composition and a perfumed consumer product including such a delivery system.

TECHNICAL FIELD OF THE INVENTION

The present invention is in the field of perfume delivery systems. In particular, the present invention relates to a delivery system comprising a biodegradable carrier and a perfume formulation and a perfuming composition and a perfumed consumer product comprising such delivery system.

BACKGROUND OF THE INVENTION

One of the problems faced by the perfumery industry lies in the relatively rapid loss of olfactive benefit provided by odoriferous compounds due to their high volatility, particularly that of “top-notes”. In order to tailor the release rates of volatiles, delivery system such as microcapsules containing active ingredients, for example a perfume, are needed to protect and later release the core payload when triggered. A key requirement from the industry regarding these systems is to survive suspension in challenging bases without physically dissociating or degrading. This is referred to as chemical stability of a delivery system. For instance, fragrance personal and household cleansers containing high levels of aggressive surfactant detergents are very challenging for the stability of delivery systems, such as microcapsules. High levels of surfactants also increase the speed of diffusion of actives out of the delivery system, such as a microcapsule. This leads to leakage of the actives during storage and a reduced impact when the microcapsules are triggered to release.

One further problem faced by the perfumery industry lies in providing delivery systems which are biodegradable in order to provide ecological and sustainable perfuming compositions and perfumed consumer products.

Delivery systems such as microcapsules providing chemical stability for a delivery system are known from the prior art, but there is still a need in the industry for improving the biodegradability and at the same time provide a certain degree of stability for a delivery system and reducing the leakage of a perfume from the delivery system and preferably providing an improved impact of the perfume upon release to the consumer.

The present invention satisfies these and other needs of the industry.

DETAILED DESCRIPTION OF THE INVENTION

In a first aspect, the present invention relates to a delivery system comprising a biodegradable carrier and a perfume formulation, wherein the carrier has a biodegradability of at least 60% within 60 days according to OECD301F.

By delivery system it is herein understood to protect active ingredients, in particular of a perfume formulation and the perfume comprised within the perfume formulation, and/or to control their release.

By carrier or carrier material is herein understood that the material of the carrier is suitable to entrap, encapsulate or hold a certain amount of perfume formulation. In order to be qualified as a carrier material, the carrier material has to entrap, encapsulate or hold a certain amount of perfume.

Typically, when the delivery system is in a matrix form, the carrier material is a matrix material and the delivery system has to entrap preferably at least 20 wt. %, preferably at least 30 wt. %, even more preferably at least 35 wt. % of the perfume formulation, based on the total weight of the delivery system.

Typically, when the delivery system is in the form a core-shell microcapsule, the carrier is a shell and the delivery system has to entrap preferably at least 80 wt. %, preferably at least 90 wt. %, of the perfume formulation, based on the total weight of the delivery system.

According to an embodiment, the carrier material does not allow a leakage more than 40%, preferably not more than 35% of the perfume formulation after 15 days at 37° C., preferably after 30 days at 37° C., preferably in a fabric softener or in a liquid detergent.

In a particular embodiment, the carrier or carrier material is a solid carrier material, i.e. an emulsion or solvent is not a carrier or carrier material.

In a particular embodiment, the delivery system is a core-shell microcapsule or the delivery system is in a matrix form (i.e. oil entrapped within a polymeric matrix, for example a monomeric, oligomeric or polymeric carrier matrix), preferably wherein the delivery system is a core-shell microcapsule having a biodegradable shell. For the sake of clarity, thereby it is understood that when the delivery system is a core-shell microcapsule, the perfume formulation is comprised in the core which is surrounded or entrapped by the biodegradable shell. When the delivery system is in the form of a matrix, the perfume formulation is entrapped in a biodegradable matrix of a carrier, such as a monomeric, oligomeric or polymeric carrier matrix, by adsorption in the matrix.

In case the carrier is a biodegradable monomeric, oligomeric or polymeric carrier matrix, it is herein understood that the perfume formulation is entrapped in the biodegradable monomeric, oligomeric or polymeric carrier matrix by adsorption within the biodegradable monomeric, oligomeric or polymeric carrier matrix, i.e. it is adsorbed in the pores of the biodegradable monomeric, oligomeric or polymeric carrier matrix.

In a particular embodiment, the biodegradable carrier material comprises a biodegradable monomeric, oligomeric or polymeric carrier material, or mixtures of two or more of these. An oligomeric carrier is a carrier wherein 2-10 monomeric units are linked by covalent bonds. For example, if the oligomeric carrier is a carbohydrate, the oligomeric carrier may be sucrose, lactose, raffinose, maltose, trehalose, fructo-oligosaccharides.

Examples of a monomeric carrier materials are glucose, fructose, mannose, galactose, arabinose, fucose, sorbitol, mannitol, for example.

Polymeric carriers have more than 10 monomeric units that are linked by covalent bonds.

In a particular embodiment, the carrier may be a biodegradable polymeric carrier material. Non-limiting examples of polymeric carrier material includes polyaspartate, modified polysuccinimides, lignin and its derivatives, polyoxazoline, polyhydroxyalcanoates, polyphenols, natural and synthetic clays, polyvinyl acetates, polyvinyl alcohol, dextrines, maltodextrines, glucose syrups, natural or modified starch, polysaccharides, carbohydrates, chitosan, gum Arabic, polyethylene glycol, polyvinyl pyrrolidone, polyvinyl alcohol, acrylamides, acrylates, polyacrylic acid and related, maleic anhydride copolymers, amine-functional polymers, vinyl ethers, styrenes, polystyrenesulfonates, vinyl acids, ethylene glycol-propylene glycol block copolymers, vegetable gums, gum acacia, pectins, xanthanes, alginates, carragenans or cellulose derivatives, such as carboxymethyl methylcellulose, methylcellulose or hydroxyethyl cellulose; chitin, proteins (animal and vegetal), polyaspartate, poylsuccinimides and its derivatives, polyesters, polyaminoesters, polyhydroxyalkanoates, polycarbonates and mixture thereof. Preferably the polymeric carrier material comprises natural or modified starch, maltodextrins, carbohydrates, chitin, proteins (animal and vegetal), polyaspartate, poylsuccinimides and its derivatives, polyesters, polyaminoesters, polyhydroxyalkanoates, polycarbonates and mixtures thereof.

The biodegradable carrier material is preferably present in an amount between 25 and 80 wt. %, preferably between 30 and 60 wt. % and more preferably between 40 and 55 wt. % (based on the total weight of the delivery system).

In a preferred embodiment, the polymeric carrier material may further comprise a fireproofing agent, preferably selected from the group consisting of sodium silicate, potassium silicate, sodium carbonate, sodium hydrogencarbonate, monoammonium phosphate or carbonate, diammonium phosphate, mono-, di- or trisodium phosphate, sodium hypophosphite, melamine cyanurate, chlorinated hydrocarbons, talc and mixtures thereof.

In case the delivery system is a core-shell microcapsule having a biodegradable shell, it is herein understood that the perfume formulation is comprised in the core which is surrounded by a biodegradable shell of the microcapsule.

The nature of the biodegradable shell of the microcapsules of the invention can vary.

As non-limiting examples, the biodegradable shell can comprise a material selected from the group consisting of polyurea, polyurethane, polyamide, polyhydroxyalkanoates, polyacrylate, polyesters, polyaminoesters, polyepoxides, polysiloxane, polycarbonate, polysulfonamide, urea formaldehyde, melamine formaldehyde resin, melamine formaldehyde resin cross-linked with polyisocyanate or aromatic polyols, melamine urea resin, melamine glyoxal resin, gelatin/gum arabic shell wall, and mixtures thereof.

In a first particular embodiment of the core-shell microcapsules, the core-shell microcapsule comprises a coacervate shell.

In a particular embodiment, the coacervate comprises a first polyelectrolyte and a second polyelectrolyte.

A first polyelectrolyte (Polyelectrolyte I) of one charge, preferably selected among proteins (such as gelatin), polypeptides or polysaccharides (such as chitosan) that are able to interact with an electrolyte or polyelectrolyte that has an opposite charge to thus form a coacervate phase having the ability to coat hydrophobic interfaces in order to form the capsules. In a preferred embodiment, Polyelectrolyte I is positively charged for pH<8 and optionally forms gels or highly viscous solutions in water below the gelling temperature, and lower viscosity solutions in water at a temperature above the melting point of the gel. The viscosity above the gelling temperature is typically lower than 0.1 Pa·s; below the gelling temperature, the elastic modulus G′ of the gel is typically in the range 0.1-15 kPa when measured during the first 24 hours after gel formation, using the measurement methods based on shear rheometry (such methods, along with the definitions relevant for the gelling temperature, are described, for example, in Parker, A. and Normand, V., Soft Matter, 6, pp 4916-4919 (2010). Preferably, Polyelectrolyte I is a gelatin material.

A second polyelectrolyte (Polyelectrolyte II), which is preferably selected among polysaccharides or another polymer bearing charges of opposite sign compared to Polyelectrolyte I. Generally, Polyelectrolyte II is negatively charged for pH>2. Preferably; such polyelectrolytes are, for example, alginate salts, cellulose derivatives guar gum, pectinate salts, carrageenan, polyacrylic and methacrylic acid or xanthan gum, or yet plant gums such as acacia gum. Most preferably, it is acacia gum (gum arabic).

The ratio between polyelectrolyte 1 and polyelectrolyte 2 is preferably comprised between 10/0.1 to 0.1/10, preferably between 10/1 and 1/10 and more preferably between 6/1 and 1/6.

According to a particular embodiment, the first polyelectrolyte carries a net positive charge when the pH is less than 8 while the second polyelectrolyte carries a net negative charge when the pH is greater than 2.

According to a particular embodiment, the first polyelectrolyte is gelatin and the second polyelectrolyte is selected from the group consisting of gum arabic, xanthan, alginate salts, cellulose derivatives, for example carboxymethyl cellulose, sodium carboxymethyl guar gum, pectinate salts, carrageenan, polyacrylic and methacrylic acid, xanthan gum and plant gums and/or mixtures thereof.

According to a preferred embodiment, the first polyelectrolyte is gelatin and the second is gum Arabic.

According to an embodiment, the coacervate material is present as a gel. According to a particular embodiment, the coacervate first material is a gel formed by providing conditions sufficient to induce gelation of either the first, the second, or both polyelectrolytes. Gelation may be induced by lowering the temperature below the gelling temperature of one of the polyelectrolytes, as detailed above and in the references cited in the previous section. For ionically cross-linkable polyelectrolytes such as chitosan, gelation may be induced by adding appropriate counter-ions such as tri-polyphosphate.

According to a preferred embodiment, the coacervate first material is hardened chemically using a suitable cross-linker such as glutaraldehyde, glyoxal, formaldehyde, tannic acid or genipin. According to another preferred embodiment, the coacervate first material is hardened enzymatically using an enzyme such as transglutaminase

According to another embodiment, the coacervate is not cross-linked.

In a particular embodiment of the core-shell microcapsules, the core-shell microcapsule comprises an oil based core comprising the perfume formulation and a composite shell comprising a first material and a second material, wherein the first material and the second material are different, the first material is a coacervate, the second material is a polymeric material. According to an embodiment, the second polymeric material is selected from the group consisting of polyurea, polyurethane, polyamide, polyester, polyacrylate, polysiloxane, polycarbonate, polysulfonamide, polymers of urea and formaldehyde, melamine and formaldehyde, melamine and urea, or melamine and glyoxal and mixtures thereof.

According to a particular embodiment, the second material is polyurea and/or polyurethane.

According to an embodiment, the second material is present in an amount less than 3%, preferably less than 1% by weight based on the total weight of the microcapsule slurry. Indeed, it has been underlined that even with a reduced amount of the second material forming the wall, microcapsules still show good stability in consumer products.

In another particular embodiment, a core-shell as defined above, based on an inner shell of a polymeric material and an outer shell of a coacervate is excluded from the present invention.

In a second particular embodiment of the core-shell microcapsules, the core-shell microcapsule comprises

-   -   an oil-based core comprising the perfume formulation     -   optionally an inner shell made of a polymerized polyfunctional         monomer;     -   a biopolymer shell comprising a protein, wherein at least one         protein is cross-linked.

According to an embodiment, the protein is chosen in the group consisting of milk proteins, caseinate salts such as sodium caseinate or calcium caseinate, casein, whey protein, hydrolyzed proteins, gelatins, gluten, pea protein, soy protein, silk protein and mixtures thereof.

According to an embodiment, the protein comprises sodium caseinate, preferably cross-linked sodium caseinate.

According to an embodiment, the protein comprises sodium caseinate and a globular protein, preferably chosen in the group consisting of whey protein, beta-lactoglobulin, ovalbumine, bovine serum albumin, vegetable proteins, and mixtures thereof.

The protein is preferably a mixture of sodium caseinate and whey protein.

According to an embodiment, the biopolymer shell comprises a crosslinked protein chosen in the group consisting of sodium caseinate and/or whey protein.

According to a particular embodiment, the microcapsules slurry comprises at least one microcapsule made of:

-   -   an oil-based core comprising the perfume formulation     -   an inner shell made of a polymerized polyfunctional monomer;         preferably a polyisocyanate having at least two isocyanate         functional groups     -   a biopolymer shell comprising a protein, wherein at least one         protein is cross-linked; wherein the protein contains preferably         a mixture comprising sodium caseinate and a globular protein,         preferably whey protein.     -   optionally at least an outer mineral layer.

According to an embodiment, sodium caseinate and/or whey protein is (are) cross-linked protein(s).

The weight ratio between sodium caseinate and whey protein is preferably comprised between 0.01 and 100, preferably between 0.1 and 10, more preferably between 0.2 and 5.

In another particular embodiment, a core-shell as defined above, based on an inner shell of a polymeric material and a biopolymer shell comprising a protein is excluded from the present invention.

In another particular embodiment of the core-shell microcapsules, the core-shell microcapsule is a polyamide core-shell polyamide microcapsule comprising:

-   -   an oil based core comprising the perfume formulation, and     -   a polyamide shell comprising:         -   an acyl chloride,         -   a first amino compound, and         -   a second amino compound.

According to a particular embodiment, the polyamide core-shell microcapsule comprises:

an oil based core comprising the perfume formulation, and

a polyamide shell comprising:

-   -   an acyl chloride, preferably in an amount comprised between 5         and 98%, preferably between 20 and 98%, more preferably between         30 and 85% w/w     -   a first amino compound, preferably in an amount comprised         between 1% and 50% w/w, preferably between 7 and 40% w/w;     -   a second amino compound, preferably in an amount comprised         between 1% and 50% w/w, preferably between 2 and 25% w/w     -   a stabilizer, preferably a biopolymer, preferably in an amount         comprised between 0 and 90%, preferably between 0.1 and 75%,         more preferably between 1 and 70%.

According to a particular embodiment, the polyamide core-shell microcapsule comprises:

-   -   an oil based core comprising the perfume formulation, and     -   a polyamide shell comprising:         -   an acyl chloride,         -   a first amino-compound being an amino-acid, preferably             chosen in the group consisting of L-Lysine, L-Arginine,             L-Histidine, L-Tryptophane and/or mixture thereof.         -   a second amino compound chosen in the group consisting of             ethylene diamine, diethylene triamine, cystamine and/or             mixture thereof, and         -   a biopolymer chosen in the group consisting of casein,             sodium caseinate, bovin serum albumin, whey protein, and/or             mixture thereof.

The first amino-compound is different from the second amino-compound.

In another particular embodiment, a polyamide core-shell as defined above, is excluded from the present invention.

According to a particular embodiment of the invention, microcapsules according to the invention comprise an outer coating material selected from the group consisting of a polysaccharide, a cationic polymer and mixtures thereof to form an outer coating to the microcapsule.

Polysaccharide polymers are well known to a person skilled in the art. Preferred nonionic polysaccharides are selected from the group consisting of locust bean gum, xyloglucan, guar gum, hydroxypropyl guar, hydroxypropyl cellulose and hydroxypropyl methyl cellulose, pectin and mixtures thereof.

According to a particular embodiment, the coating consists of a cationic coating.

Cationic polymers are also well known to a person skilled in the art. Preferred cationic polymers have cationic charge densities of at least 0.5 meq/g, more preferably at least about 1.5 meq/g, but also preferably less than about 7 meq/g, more preferably less than about 6.2 meq/g. The cationic charge density of the cationic polymers may be determined by the Kjeldahl method as described in the US Pharmacopoeia under chemical tests for Nitrogen determination. The preferred cationic polymers are chosen from those that contain units comprising primary, secondary, tertiary and/or quaternary amine groups that can either form part of the main polymer chain or can be borne by a side substituent directly connected thereto. The weight average (Mw) molecular weight of the cationic polymer is preferably between 10,000 and 3.5M Dalton, more preferably between 50,000 and 2M Dalton.

According to a particular embodiment, one will use cationic polymers based on acrylamide, methacrylamide, N-vinylpyrrolidone, quaternized N,N-dimethylaminomethacrylate, diallyldimethylammonium chloride, quaternized vinylimidazole (3-methyl-1-vinyl-1H-imidazol-3-ium chloride), vinylpyrrolidone, acrylamidopropyltrimonium chloride, cassia hydroxypropyltrimonium chloride, guar hydroxypropyltrimonium chloride or polygalactomannan 2-hydroxypropyltrimethylammonium chloride ether, starch hydroxypropyltrimonium chloride and cellulose hydroxypropyltrimonium chloride. Preferably copolymers shall be selected from the group consisting of polyquaternium-5, polyquaternium-6, polyquaternium-7, polyquaternium10, polyquaternium-11, polyquaternium-16, polyquaternium-22, polyquaternium-28, polyquaternium-43, polyquaternium-44, polyquaternium-46, cassia hydroxypropyltrimonium chloride, guar hydroxypropyltrimonium chloride or polygalactomannan 2-hydroxypropyltrimethylammonium chloride ether, starch hydroxypropyltrimonium chloride and cellulose hydroxypropyltrimonium chloride.

As specific examples of commercially available products, one may cite Salcare® SC60 (cationic copolymer of acrylamidopropyltrimonium chloride and acrylamide, origin: BASF) or Luviquat®, such as the PQ 11N, FC 550 or Style (polyquaternium-11 to 68 or quaternized copolymers of vinylpyrrolidone origin: BASF), or also the Jaguar® (C13S or C17, origin Rhodia).

According to any one of the above embodiments of the invention, there is added an amount of polymer described above comprised between about 0% and 5% w/w, or even between about 0.1% and 2% w/w, percentage being expressed on a w/w basis relative to the total weight of the microcapsule. It is clearly understood by a person skilled in the art that only part of said added polymers will be incorporated into/deposited on the microcapsule shell.

In a particular embodiment, the biodegradable carrier, preferably being either a biodegradable shell or a biodegradable monomeric, oligomeric or polymeric matrix material, has a biodegradability of at least 65%, 70%, 75%, 80%, 85%, 90%, 95% or 98% within 60 days according to OECD301F.

OECD301F is a standard test method on the biodegradability from the Organisation of Economic Co-operation and Development.

In a particular embodiment, the perfume formulation comprises

-   -   0 to 60 wt. % of a hydrophobic solvent (based on the total         weight of the perfume formulation),     -   40 to 100 wt. % of a perfume oil (based on the total weight of         the perfume formulation),     -   optionally, other active ingredients.

By “perfuming formulation” it is herein understood a formulation which is for fine and functional perfumery. In particular, perfuming ingredients, solvents or adjuvants of current use can be combined for the preparation of a perfume formulation.

The perfuming ingredients may be dissolved in a solvent of current use in the perfume industry. The solvent is preferably not an alcohol. Examples of such solvents are diethyl phthalate, isopropyl myristate, Abalyn® (rosin resins, available from Eastman), benzyl benzoate, ethyl citrate, limonene or other terpenes, triacetin, or, preferably Abalyn®, benzyl benzoate, limonene or other terpenes, or isoparaffins.

Preferably, the solvent is very hydrophobic and highly sterically hindered, like for example Abalyn® or benzyl benzoate. Preferably the perfume comprises less than 30% of solvent. More preferably the perfume comprises less than 20% and even more preferably less than 10% of solvent, all these percentages being defined by weight relative to the total weight of the perfume. Most preferably, the perfume is essentially free of solvent.

According to a particular embodiment, the hydrophobic solvent is a density balancing material preferably chosen in the group consisting of benzyl salicylate, benzyl benzoate, cyclohexyl salicylate, benzyl phenylacetate, phenylethyl phenylacetate, triacetin, ethyl citrate, methyl and ethyl salicylate, benzyl cinnamate, and mixtures thereof.

A “density balancing material” should be understood as a material having a density preferably greater than 1.07 g/cm³ and having preferably low or no odor.

The density of a component is defined as the ratio between its mass and its volume (g/cm³).

Several methods are available to determine the density of a component.

One may refer for example to the ISO 298:1998 method to measure d20 densities of essential oils.

By “perfume oil” (or also “perfume”) or “flavour” is herein understood an ingredient or composition that is a liquid at about 20° C. Said perfume or flavour oil can be a perfuming or flavouring ingredient alone or a mixture of ingredients in the form of a perfuming or flavouring composition. As a “perfuming ingredient” it is meant here a compound, which is used in perfuming preparations or compositions to impart as primary purpose a hedonic effect. In other words such an ingredient, to be considered as being a perfuming one, must be recognized by a person skilled in the art as being able to at least impart or modify in a positive or pleasant way the odor of a composition, and not just as having an odor. The nature and type of the perfuming ingredients present in the oil phase do not warrant a more detailed description here, which in any case would not be exhaustive, the skilled person being able to select them on the basis of its general knowledge and according to intended use or application and the desired organoleptic effect. In general terms, these perfuming ingredients belong to chemical classes as varied as alcohols, aldehydes, ketones, esters, ethers, acetates, nitriles, terpenoids, nitrogenous or sulphurous heterocyclic compounds and essential oils, and said perfuming ingredients can be of natural or synthetic origin. Many of these ingredients are listed in reference texts such as the book by S. Arctander, Perfume and Flavor Chemicals, 1969, Montclair, N.J., USA, or its more recent versions, or in other works of a similar nature, as well as in the abundant patent literature in the field of perfumery. It is also understood that said ingredients may also be compounds known to release in a controlled manner various types of perfuming compounds.

In particular one may cite perfuming ingredients which are commonly used in perfume formulations, such as:

-   -   Aldehydic ingredients: decanal, dodecanal, 2-methyl-undecanal,         10-undecenal, octanal, nonanal and/or nonenal;     -   Aromatic-herbal ingredients: eucalyptus oil, camphor,         eucalyptol, 5-methyltricyclo[6.2.1.0˜2,7˜]undecan-4-one,         1-methoxy-3-hexanethiol, 2-ethyl-4,4-dimethyl-1,3-oxathiane,         2,2,7/8,9/10-Tetramethylspiro[5.5]undec-8-en-1-one and/or         menthol;     -   Balsamic ingredients: coumarin, ethylvanillin and/or vanillin;     -   Citrus ingredients: dihydromyrcenol, citral, orange oil, linalyl         acetate, citronellyl nitrile, orange terpenes, 1-p-menthen-8-yl         acetate and/or 1,4(8)-p-menthadiene;     -   Floral ingredients: methyl dihydrojasmonate, linalool,         citronellol, phenylethanol,         3-(4-tert-butylphenyl)-2-methylpropanal, hexylcinnamic aldehyde,         benzyl acetate, tetrahydro-2-isobutyl-4-methyl-4(2H)-pyranol,         beta ionone, methyl 2-(methylamino)benzoate,         (E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,         (1E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1-penten-3-one,         1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-buten-1-one,         (2E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one,         (2E)-1-[2,6,6-trimethyl-3-cyclohexen-1-yl]-2-buten-1-one,         (2E)-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-buten-1-one,         2,5-dimethyl-2-indanmethanol,         2,6,6-trimethyl-3-cyclohexene-1-carboxylate,         3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal, hexyl salicylate,         3,7-dimethyl-1,6-nonadien-3-ol,         3-(4-isopropylphenyl)-2-methylpropanal, verdyl acetate,         geraniol, p-menth-1-en-8-ol, 4-(1,1-dimethylethyl)-1-cyclohexyle         acetate, 1,1-dimethyl-2-phenylethyl acetate,         4-cyclohexyl-2-methyl-2-butanol, amyl salicylate, high cis         methyl dihydrojasmonate, 3-methyl-5-phenyl-1-pentanol, verdyl         proprionate, geranyl acetate, tetrahydro linalool,         cis-7-p-menthanol, propyl (S)-2-(1,1-dimethylpropoxy)propanoate,         2-methoxynaphthalene, 2,2,2-trichloro-1-phenylethyl acetate,         4/3-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carbaldehyde,         amylcinnamic aldehyde, 8-decen-5-olide, 4-phenyl-2-butanone,         isononyle acetate, 4-(1,1-dimethylethyl)-1-cyclohexyl acetate,         verdyl isobutyrate and/or mixture of methylionones isomers;     -   Fruity ingredients: gamma-undecalactone,         2,2,5-trimethyl-5-pentylcyclopentanone,         2-methyl-4-propyl-1,3-oxathiane, 4-decanolide, ethyl         2-methyl-pentanoate, hexyl acetate, ethyl 2-methylbutanoate,         gamma-nonalactone, allyl heptanoate, 2-phenoxyethyl isobutyrate,         ethyl 2-methyl-1,3-dioxolane-2-acetate,         3-(3,3/1,1-dimethyl-5-indanyl)propanal, diethyl         1,4-cyclohexanedicarboxylate, 3-methyl-2-hexen-1-yl acetate,         1-[3,3-dimethylcyclohexyl]ethyl [3-ethyl-2-oxiranyl]acetate         and/or diethyl 1,4-cyclohexane dicarboxylate;     -   Green ingredients: 2-methyl-3-hexanone (E)-oxime,         2,4-dimethyl-3-cyclohexene-1-carbaldehyde,         2-tert-butyl-1-cyclohexyl acetate, styrallyl acetate, allyl         (2-methylbutoxy)acetate, 4-methyl-3-decen-5-ol, diphenyl ether,         (Z)-3-hexen-1-ol and/or         1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one;     -   Musk ingredients: 1,4-dioxa-5,17-cycloheptadecanedione,         (Z)-4-cyclopentadecen-1-one, 3-methylcyclopentadecanone,         1-oxa-12-cyclohexadecen-2-one, 1-oxa-13-cyclohexadecen-2-one,         (9Z)-9-cycloheptadecen-1-one,         2-{1S)-1-[(1R)-3,3-dimethylcyclohexyl]ethoxy}-2-oxoethyl         propionate 3-methyl-5-cyclopentadecen-1-one,         1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-g-2-benzopyrane,         (1S,1′R)-2-[1-(3′,3′-dimethyl-1′-cyclohexyl)ethoxy]-2-methylpropyl         propanoate, oxacyclohexadecan-2-oneand/or         (1S,1′R)-[1-(3′,3′-dimethyl-1′-cyclohexyl)ethoxycarbonyl]methyl         propanoate,     -   Woody ingredients: 1-[(1         RS,6SR)-2,2,6-trimethylcyclohexyl]-3-hexanol,         3,3-dimethyl-5-[(1R)-2,2,3-trimethyl-3-cyclopenten-1-yl]-4-penten-2-ol,         3,4′-dimethylspiro[oxirane-2,9′-tricyclo[6.2.1.0²⁷]undec[4]ene,         (1-ethoxyethoxy)cyclododecane,         2,2,9,11-tetramethylspiro[5.5]undec-8-en-1-yl acetate,         1-(octahydro-2,3,8,8-tetramethyl-2-naphtalenyl)-1-ethanone,         patchouli oil, terpenes fractions of patchouli oil, Clearwood®,         (1′R,E)-2-ethyl-4-(2′,2′,3′-trimethyl-3′-cyclopenten-1′-yl)-2-buten-1-ol,         2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol,         methyl cedryl ketone,         5-(2,2,3-trimethyl-3-cyclopentenyl)-3-methylpentan-2-ol,         1-(2,3,8,8-tetramethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)ethan-1-one         and/or isobornyl acetate;     -   Other ingredients (e.g. amber, powdery spicy or watery):         dodecahydro-3a,6,6,9a-tetramethyl-naphtho[2,1-b]furan and any of         its stereoisomers, heliotropin, anisic aldehyde, eugenol,         cinnamic aldehyde, clove oil,         3-(1,3-benzodioxol-5-yl)-2-methylpropanal,         7-methyl-2H-1,5-benzodioxepin-3(4H)-one,         2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydro-2-naphthalenol,         1-phenylvinyl acetate,         6-methyl-7-oxa-1-thia-4-azaspiro[4.4]nonan and/or         3-(3-isopropyl-1-phenyl)butanal.

According to an embodiment, the perfuming formulation comprises a fragrance modulator (that can be used in addition to the hydrophobic solvent when present or as substitution of the hydrophobic solvent when there is no hydrophobic solvent).

Preferably, the fragrance modulator is defined as a fragrance material with

-   -   i. a vapor pressure of less than 0.0008 Torr at 22° C.;     -   ii. a clogP of 3.5 and higher, preferable 4.0 and higher and         more preferable 4.5     -   iii. at least two Hansen solubility parameters selected from a         first group consisting of: an atomic dispersion force from 12 to         20, a dipole moment from 1 to 7, and a hydrogen bonding from 2.5         to 11,     -   iv. at least two Hansen solubility parameters selected from a         second group consisting of: an atomic dispersion force from 14         to 20, a dipole moment from 1 to 8, and a hydrogen bonding from         4 to 11, when in solution with a compound having a vapor         pressure range of 0.0008 to 0.08 Torr at 22° C.

Preferable as examples the following ingredients can be listed as modulators but the list in not limited to the following materials: alcohol C12, oxacyclohexadec-12/13-en-2-one, 3-[(2′,2′,3′-trimethyl-3′-cyclopenten-1′-yl)methoxy]-2-butanol, cyclohexadecanone, (Z)-4-cyclopentadecen-1-one, cyclopentadecanone, (8Z)-oxacycloheptadec-8-en-2-one, 2-[5-(tetrahydro-5-methyl-5-vinyl-2-furyl)-tetrahydro-5-methyl-2-furyl]-2-propanol, muguet aldehyde, 1,5,8-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene, (++4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene, (+)-(1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexane]-2′-en-4′-one, oxacyclohexadecan-2-one, 2-{(1S)-1-[(1R)-3,3-dimethylcyclohexyl]ethoxy}-2-oxoethyl propionate, (+)-(4R,4aS,6R)-4,4a-dimethyl-6-(1-propen-2-yl)-4,4a,5,6,7,8-hexahydro-2(3H)-naphthalenone, amylcinnamic aldehyde, hexylcinnamic aldehyde, hexyl salicylate, (1E)-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,6-heptadien-3-one, (9Z)-9-cycloheptadecen-1-one.

A perfumery base according to the invention may not be limited to the above mentioned perfuming ingredients, and many other of these co-ingredients are in any case listed in reference texts such as the book by S. Arctander, Perfume and Flavor Chemicals, 1969, Montclair, N.J., USA, or its more recent versions, or in other works of a similar nature, as well as in the abundant patent literature in the field of perfumery. It is also understood that said co-ingredients may also be compounds known to release in a controlled manner various types of perfuming compounds also known as properfume or profragrance. Non-limiting examples of suitable properfume may include 4-(dodecylthio)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-butanone, 4-(dodecylthio)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butanone, trans-3-(dodecylthio)-1-(2,6,6-trimethyl-3-cyclohexen-1-yl)-1-butanone, 2-phenylethyl oxo(phenyl)acetate or a mixture thereof.

In a particular embodiment, the perfume formulation comprises a perfume oil which has at least one, preferably at least two of the following characteristics:

-   -   at least 35%, preferably at least 40%, preferably at least 50%,         more preferably at least 60% of perfuming ingredients having a         log P above 3, preferably above 3.5,     -   at least 20%, preferably at least 25%, preferably at least 30%,         more preferably at least 40% of Bulky materials of groups 1 to         6, preferably 3 to 6 as herein defined and     -   at least 15%, preferably at least 20%, more preferably at least         25%, even more preferably at least 30% of high impact perfume         materials having a Log T<−4,

In a particular embodiment, the perfume formulation comprises a perfume oil which has all of the following characteristics:

-   -   at least 35%, preferably at least 40%, preferably at least 50%,         more preferably at least 60% of perfuming ingredients having a         log P above 3, preferably above 3.5,     -   at least 20%, preferably at least 25%, preferably at least 30%,         more preferably at least 40% of Bulky materials of groups 1 to         6, preferably 3 to 6 as herein defined and     -   at least 15%, preferably at least 20%, more preferably at least         25%, even more preferably at least 30% of high impact perfume         materials having a Log T<−4,         The amounts of ingredients/materials of the perfume oil defined         above are given based on the total weight of the perfume oil.

In a particular embodiment, the perfume oil comprises at least 40% of perfuming ingredients having a log P above 3.

Log P is the common logarithm of estimated octanol-water partition coefficient, which is known as a measure of lipophilicity.

The Log P values of many perfuming compound have been reported, for example, in the Pomona92 database, available from Daylight Chemical Information Systems, Inc. (Daylight CIS), Irvine, Calif., which also contains citations to the original literature. Log P values are most conveniently calculated by the “CLOGP” program, also available from Daylight CIS. This program also lists experimental logP values when they are available in the Pomona92 database. The “calculated logP” (cLog P) is determined by the fragment approach of Hansch and Leo (cf., A. Leo, in Comprehensive Medicinal Chemistry, Vol. 4, C. Hansch, P. G. Sammens, J. B. Taylor and C. A. Ramsden, Eds., p. 295, Pergamon Press, 1990). The fragment approach is based on the chemical structure of each perfume oil ingredient, and takes into account the numbers and types of atoms, the atom connectivity, and chemical bonding. The cLog P values, which are the most reliable and widely used estimates for this physicochemical property, are preferably used instead of the experimental Log P values in the selection of perfuming compounds which are useful in the present invention.

In a particular embodiment, the perfume oil comprises at least 40%, preferably at least 50%, more preferably at least 60% of ingredients having a logP above 3, preferably above 3.5 and even more preferably above 3.75.

Preferably, the perfume oil contains less than 10% of its own weight of primary alcohols, less than 15% of its own weight of secondary alcohols and less than 20% of its own weight of tertiary alcohols. Advantageously, the perfume used in the invention does not contain any primary alcohols and contains less than 15% of secondary and tertiary alcohols.

In a particular embodiment, the perfume oil comprises at least 20%, preferably at least 25%, more preferably at least 40% of Bulky materials of groups 1 to 6, preferably 3 to 6.

The term Bulky materials is herein understood as perfuming ingredients having a high steric hindrance, i.e. having a substitution pattern which provides high steric hinderance and thus

The Bulky materials are in particular those from one of the following groups:

-   -   Group 1: perfuming ingredients comprising a cyclohexane,         cyclohexene, cyclohexanone or cyclohexenone ring substituted         with at least one 1 to 4 nodes comprising substituent,         preferably at least one linear or branched C₁ to C₄ alkyl or         alkenyl substituent;     -   Group 2: perfuming ingredients comprising a cyclopentane,         cyclopentene, cyclopentanone or cyclopentenone ring substituted         with at least one 4 or more nodes comprising substituent,         preferably at least one linear or branched Ca or longer,         preferably C₄ to C₈ alkyl or alkenyl substituent;     -   Group 3: perfuming ingredients comprising a phenyl ring or         perfuming ingredients comprising a cyclohexane, cyclohexene,         cyclohexanone or cyclohexenone ring substituted with at least         one 5 or more nodes comprising substituent, preferably at least         one linear or branched C₅ or longer, preferably C₅ to C₈, alkyl         or alkenyl substituent, or with at least one phenyl substituent         and optionally one or more 1 to 3 nodes comprising substituents,         preferably one or more linear or branched C₁ to C₃ alkyl or         alkenyl substituents;     -   Group 4: perfuming ingredients comprising at least two fused or         linked 5 membered or 6 membered rings, preferably at least two         fused or linked C₅ and/or C₆ rings;     -   Group 5: perfuming ingredients comprising a camphor-like ring         structure, i.e. two 5 or 6 membered rings that are fused in a         bridge-type fashion;     -   Group 6: perfuming ingredients comprising at least one 7 to 20         membered ring, preferably at least one C7 or C20 ring structure.

The term nodes as understood in this context means any atom which is able to provide at least two, preferably at least 3, more preferably 4, bonds to further atoms. Particular examples of nodes as herein understood are carbon atoms (up to 4 bonds to further atoms), nitrogen atoms (up to 3 bonds to further atoms), oxygen atoms (up to 2 bonds to further atoms) and sulfur (up to 2 bonds to further atoms). Particular examples of further atoms as understood in this context could be carbon atoms, nitrogen atoms, sulfur atoms, oxygen atoms and hydrogen atoms.

Examples of ingredients from each of these groups are:

-   -   Group 1: 2,4-dimethyl-3-cyclohexene-1-carbaldehyde (origin:         Firmenich SA, Geneva, Switzerland), isocyclocitral, menthone,         isomenthone, Romascone® (methyl         2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate, origin:         Firmenich SA, Geneva, Switzerland), nerone, terpineol,         dihydroterpineol, hexylate, rose oxide, Perycorolle®         ((S)-1,8-p-menthadiene-7-ol, origin: Firmenich SA, Geneva,         Switzerland), 1-p-menthene-4-ol, (1 RS,3RS,4SR)-3-p-mentanyl         acetate, cyclohexyl acetate,         2,4,6-trimethyl-3-cyclohexene-1-carbaldehyde, para         tert-butylcyclohexanone, menthenethiol,         2-tert-butyl-1-cyclohexyl acetate (origin: International Flavors         and Fragrances, USA), Lorysia®         (4-(1,1-dimethylethyl)-1-cyclohexyl acetate, origin: Firmenich         SA, Geneva, Switzerland);     -   Group 2:         (E)-3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol         (origin: Givaudan SA, Vernier, Switzerland),         (1′R,E)-2-ethyl-4-(2′,2′,3′-trimethyl-3′-cyclopenten-1′-yl)-2-buten-1-ol         (origin: Firmenich SA, Geneva, Switzerland), Polysantol®         ((1′R,E)-3,3-dimethyl-5-(2′,2′,3′-trimethyl-3′-cyclopenten-1′-yl)-4-penten-2-ol,         origin: Firmenich SA, Geneva, Switzerland), fleuramone, Hedione®         HC (methyl-cis-3-oxo-2-pentyl-1-cyclopentane acetate, origin:         Firmenich SA, Geneva, Switzerland), Veloutone®         (2,2,5-Trimethyl-5-pentyl-1-cyclopentanone, origin: Firmenich         SA, Geneva, Switzerland), Nirvanol®         (3,3-dimethyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol,         origin: Firmenich SA, Geneva, Switzerland),         3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-pentanol         (origin, Givaudan SA, Vernier, Switzerland), dartanol, fructone;     -   Group 3: Neobutenone®         (1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, origin:         Firmenich SA, Geneva, Switzerland), nectalactone ((1′         R)-2-[2-(4′-methyl-3′-cyclohexen-1′-yl)propyl]cyclopentanone),         Dynascone® (mixture of         1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one and         1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, origin:         Firmenich SA, Geneva, Switzerland), Romandolide®         ((1S,1′R)-[1-(3′,3′-Dimethyl-1′-cyclohexyl)ethoxycarbonyl]methyl         propanoate, origin: Firmenich SA, Geneva, Switzerland),         Limbanol® (1-(2,2,3,6-tetramethyl-cyclohexyl)-3-hexanol, origin:         Firmenich SA, Geneva, Switzerland),         trans-1-(2,2,6-trimethyl-1-cyclohexyl)-3-hexanol (origin:         Firmenich SA, Geneva, Switzerland),         (E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,         terpenyl isobutyrate, 8-methoxy-1-p-menthene, Helvetolide®         ((1S,1′R)-2-[1-(3′,3′-dimethyl-1′-cyclohexyl)         ethoxy]-2-methylpropyl propanoate, origin: Firmenich SA, Geneva,         Switzerland),         1-methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carbaldehyde,         allyl cyclohexylpropionate, 2-methoxy-4-methylphenyl methyl         carbonate, ethyl 2-methoxy-4-methylphenyl carbonate,         4-ethyl-2-methoxyphenyl methyl carbonate, Doremox®         (tetrahydro-4-methyl-2-phenyl-2H-pyran, origin: Firmenich SA,         Geneva, Switzerland), 2,4,6-trimethyl-4-phenyl-1,3-dioxane,         terpenyl acetate, dihydroterpenyl acetate, cyclanol acetate,         Fructalate® (1,4-cyclohexane diethyldicarboxylate, origin:         Firmenich SA, Geneva, Switzerland), alpha-ionone, beta-ionone,         damascenone, damascones, Floralozone, Peonile, amylcinnamic         aldehdye, hexylcinnamic aldehyde, benzyl cinnamate, amyl         salicylate, hexyl salicylate, MPGE (=ethyl         2,3-epoxy-3-phenylbutanoate) Dorysane;     -   Group 4: vetyverone,         1-(octahydro-2,3,8,8-tetramethyl-2-naphtalenyl)-1-ethanone         (origin: International Flavors and Fragrances, USA),         (5RS,9RS,10SR)-2,6,9,10-tetramethyl-1-oxaspiro[4.5]deca-3,6-diene         and the (5RS,9SR,10RS) isomer,         6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene,         1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4-indenone (origin:         International Flavors and Fragrances, USA), Hivernal® (a mixture         of 3-(3,3-dimethyl-5-indanyl)propanal and         3-(1,1-dimethyl-5-indanyl)propanal, origin: Firmenich SA,         Geneva, Switzerland), Polywood®         (perhydro-5,5,8A-trimethyl-2-naphthalenyl acetate, origin:         Firmenich SA, Geneva, Switzerland), octalynol, Cetalox®         (dodecahydro-3a,6,6,9a-tetramethyl-naphtho[2,1-b]furan, origin:         Firmenich SA, Geneva, Switzerland), Koumalactone®         ((3ARS,6SR,7ASR)-perhydro-3,6-dimethyl-benzo[B]furan-2-one,         origin: Firmenich SA, Geneva, Switzerland), Natactone®         ((6R)-perhydro-3,6-dimethyl-benzo[B]furan-2-one, origin:         Firmenich SA, Geneva, Switzerland), yara yara, bromelia,         heliopropanal, octahydrocoumarine, galaxolide;     -   Group 5: camphor, borneol, isobornyl acetate,         8-isopropyl-6-methyl-bicyclo[2.2.2]oct-5-ene-2-carbaldehyde,         Florex® (mixture of         9-ethylidene-3-oxatricyclo[6.2.1.0(2,7)]undecan-4-one and         10-ethylidene-3-oxatricyclo[6.2.1.0(2,7)]undecan-4-one, origin:         Firmenich SA, Geneva, Switzerland),         (1R,2S,4R)-4,6,6-trimethyl-bicyclo[3,1,1]heptan-2-ol, nopyl         acetate, patchoulol, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl acetate         and tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl acetate as well as         tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate and         tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate, eucalyptol,         Rhubofix®         (3′,4-dimethyl-tricyclo[6.2.1.0(2,7)]undec-4-ene-9-spiro-2′-oxirane,         origin: Firmenich SA, Geneva, Switzerland),         9/10-ethyldiene-3-oxatricyclo[6.2.1.0(2,7)]undecane, Verdylate,         (+)-(1S,2S,3S)-2,6,6-trimethyl-bicyclo[3.1.1]heptane-3-spiro-2′-cyclohexen-4′-one     -   Group 6: Cedroxyde®         (trimethyl-13-oxabicyclo-[10.1.0]-trideca-4,8-diene, origin:         Firmenich SA, Geneva, Switzerland), Ambrettolide LG         ((E)-9-hexadecen-16-olide, origin: Firmenich SA, Geneva,         Switzerland), Habanolide® (pentadecenolide, origin: Firmenich         SA, Geneva, Switzerland), muscenone         (3-methyl-(4/5)-cyclopentadecenone, origin: Firmenich SA,         Geneva, Switzerland), muscone (origin: Firmenich SA, Geneva,         Switzerland), Exaltolide® (pentadecanolide, origin: Firmenich         SA, Geneva, Switzerland), Exaltone® (cyclopentadecanone, origin:         Firmenich SA, Geneva, Switzerland),         (1-ethoxyethoxy)cyclododecane (origin: Firmenich SA, Geneva,         Switzerland), Astrotone, 4,8-cyclododecadien-1-one, Methyl         cedryl ketone (origin: International Flavors and Fragrances,         USA), vetyverol, cedramber         (8-methoxy-2,6,6,8-tetramethyl-tricyclo[5.3.1.0(1,5)]undecane,         origin: Firmenich SA, Geneva, Switzerland), cedrene, cedrenol,         cedrol, 3-methoxy-7,7-dimethyl-10-methylene-bicyclo[4.3.1]decane         (origin: Firmenich SA, Geneva, Switzerland).

Preferably, the perfume oil comprises at least 25%, preferably at least 30%, preferably at least 40%, preferably at least 50%, more preferably at least 60% of ingredients selected from Groups 1 to 6, as defined above. More preferably said perfume comprises at least 30%, preferably at least 40%, preferably at least 50% of ingredients from Groups 3 to 6, as defined above. Most preferably said perfume comprises at least 30%, preferably at least 50% of ingredients from Groups 3, 4 or 6, as defined above.

In a particular embodiment, the perfume oil comprises at least 15% of high impact perfume materials having a Log T<−4.

“High impact perfume raw materials” should be understood as perfume raw materials having a LogT<−4. The odor threshold concentration of a chemical compound is determined in part by its shape, polarity, partial charges and molecular mass. For convenience, the threshold concentration is presented as the common logarithm of the threshold concentration, i.e., Log [Threshold] (“LogT”).

The odor threshold concentration of a perfuming compound is determined by using a gas chromatograph (“GC”). Specifically, the gas chromatograph is calibrated to determine the exact volume of the perfume oil ingredient injected by the syringe, the precise split ratio, and the hydrocarbon response using a hydrocarbon standard of known concentration and chain-length distribution. The air flow rate is accurately measured and, assuming the duration of a human inhalation to last 12 seconds, the sampled volume is calculated. Since the precise concentration at the detector at any point in time is known, the mass per volume inhaled is known and hence the concentration of the perfuming compound. To determine the threshold concentration, solutions are delivered to the sniff port at the back-calculated concentration. A panelist sniffs the GC effluent and identifies the retention time when odor is noticed. The average across all panelists determines the odor threshold concentration of the perfuming compound. The determination of odor threshold is described in more detail in C. Vuilleumier et al., Multidimensional Visualization of Physical and Perceptual Data Leading to a Creative Approach in Fragrance Development, Perfume & Flavorist, Vol. 33, September, 2008, pages 54-61.

According to a particular embodiment, the high impact perfume raw materials having a Log T<−4 are selected from the list in Table A below.

TABLE A high impact perfume raw materials having a Log T < −4 Perfume raw materials (Log T < −4) (+−)-1-METHOXY-3-HEXANETHIOL 4-(4-HYDROXY-1-PHENYL)-2-BUTANONE (+−)-2-(4-METHYL-3-CYCLOHEXEN-1-YL)-2-PROPANETHIOL 2-METHOXY-4-(1-PROPENYL)-1-PHENYL ACETATE PYRAZOBUTYLE 3-PROPYLPHENOL 1-(3-METHYL-1-BENZOFURAN-2-YL)ETHANONE 2-(3-PHENYLPROPYL)PYRIDINE 1-(3,3-DIMETHYL-1-CYCLOHEXEN-1-YL)-4-PENTEN-1-ONE (A) + 1- (5,5-DIMETHYL-1-CYCLOHEXEN-1-YL)-4-PENTEN-1-ONE (B) 1-(5,5-DIMETHYL-1-CYCLOHEXEN-1-YL)-4-PENTEN-1-ONE (3RS,3ARS,6SR,7ASR)-PERHYDRO-3,6-DIMETHYL- BENZO[B]FURAN-2-ONE (A) + (3SR,3ARS,6SR,7ASR)-PERHYDRO- 3,6-DIMETHYL-BENZO[B]FURAN-2-ONE (B) (+−)-1-(5-ETHYL-5-METHYL-1-CYCLOHEXEN-1-YL)-4-PENTEN-1- ONE (1′S,3′R)-1-METHYL-2-[(1′,2′,2′-TRIMETHYLBICYCLO[3.1.0]HEX-3′- YL)METHYL]CYCLOPROPYL}METHANOL (+−)-3-MERCAPTOHEXYL ACETATE (2E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1- ONE 7-METHYL-2H-1,5-BENZODIOXEPIN-3(4H)-ONE (2E,6Z)-2,6-NONADIEN-1 -OL (4Z)-4-DODECENAL (+−)-4-HYDROXY-2,5-DIMETHYL-3(2H)-FURANONE METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE 3-METHYLINDOLE (+−)-PERHYDRO-4ALPHA,8ABETA-DIMETHYL-4A-NAPHTHALENOL PATCHOULOL 2-METHOXY-4-(1-PROPENYL)PHENOL (+−)-5,6-DIHYDRO-4-METHYL-2-PHENYL-2H-PYRAN (A) + TETRAHYDRO-4-METHYLENE-2-PHENYL-2H-PYRAN (B) 4-METHYLENE-2-PHENYLTETRAHYDRO-2H-PYRAN (A) + (+−)-4- METHYL-2-PHENYL-3,6-DIHYDRO-2H-PYRAN (B) 4-HYDROXY-3-METHOXYBENZALDEHYDE NONYLENIC ALDEHYDE 2-METHOXY-4-PROPYLPHENOL (2Z)-3-METHYL-5-PHENYL-2-PENTENENITRILE (A) + (2E)-3- METHYL-5-PHENYL-2-PENTENENITRILE (B) 1-(SPIRO[4.5]DEC-6-EN-7-YL)-4-PENTEN-1-ONE (A) + 1- (SPIRO[4.5]DEC-7-EN-7-YL)-4-PENTEN-1-ONE (B) 2-METHOXYNAPHTHALENE (−)-(3AR,5AS,9AS,9BR)-3A,6,6,9A- TETRAMETHYLDODECAHYDRONAPHTHO[2,1-B]FURAN 5-NONANOLIDE (3AR,5AS,9AS,9BR)-3A,6,6,9A- TETRAMETHYLDODECAHYDRONAPHTHO[2,1-B]FURAN 7-ISOPROPYL-2H,4H-1,5-BENZODIOXEPIN-3-ONE COUMARIN 4-METHYLPHENYL ISOBUTYRATE (2E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE BETA,2,2,3-TETRAMETHYL-DELTA-METHYLENE-3- CYCLOPENTENE-1-BUTANOL DELTA DAMASCONE ((2E)-1-[(1RS,2SR)-2,6,6-TRIMETHYL-3- CYCLOHEXEN-1-YL]-2-BUTEN-1-ONE) (+−)-3,6-DIHYDRO-4,6-DIMETHYL-2-PHENYL-2H-PYRAN ANISALDEHYDE PARACRESOL 3-ETHOXY-4-HYDROXYBENZALDEHYDE METHYL 2-AMINOBENZOATE ETHYL METHYLPHENYLGLYCIDATE OCTALACTONE G ETHYL 3-PHENYL-2-PROPENOATE (−)-(2E)-2-ETHYL-4-[(1R)-2,2,3-TRIMETHYL-3-CYCLOPENTEN-1-YL]- 2-BUTEN-1-OL PARACRESYL ACETATE DODECALACTONE TRICYCLONE (+)-(3R,5Z)-3-METHYL-5-CYCLOPENTADECEN-1-ONE UNDECALACTONE (1R,4R)-8-MERCAPTO-3-P-MENTHANONE (3S,3AS,6R,7AR)-3,6-DIMETHYLHEXAHYDRO-1-BENZOFURAN- 2(3H)-ONE BÉTA IONONE (+−)-6-PENTYLTETRAHYDRO-2H-PYRAN-2-ONE (3E,5Z)-1,3,5-UNDECATRIENE 10-UNDECENAL (A) + (9E)-9-UNDECENAL (B) + (9Z)-9-UNDECENAL (C) (Z)-4-DECENAL (+−)-ETHYL 2-METHYLPENTANOATE 1,2-DIALLYLDISULFANE (2Z)-2-TRIDECENENITRILE (A) + (3Z)-3-TRIDECENENITRILE (B) + (3E)-3-TRIDECENENITRILE (C) + (2E)-2-TRIDECENENITRILE (D) (+−)-2-ETHYL-4,4-DIMETHYL-1,3-OXATHIANE (+)-(3R,5Z)-3-METHYL-5-CYCLOPENTADECEN-1-ONE 3-(4-TERT-BUTYLPHENYL)PROPANAL ALLYL (CYCLOHEXYLOXY)ACETATE METHYLNAPHTHYLKETONE (+−)-(4E)-3-METHYL-4-CYCLOPENTADECEN-1-ONE (A) + (+−)-(5E)-3- METHYL-5-CYCLOPENTADECEN-1-ONE (B) + (+−)-(5Z)-3-METHYL-5- CYCLOPENTADECEN-1-ONE (C) CYCLOPROPYLMETHYL (3Z)-3-HEXENOATE (A) + CYCLOPROPYLMETHYL (3E)-3-HEXENOATE (B) (4E)-4-METHYL-5-(4-METHYLPHENYL)-4-PENTENAL (+−)-1-(5-PROPYL-1,3-BENZODIOXOL-2-YL)ETHANONE 4-METHYL-2-PENTYLPYRIDINE (+−)-(E)-3-METHYL-4-(2,6,6-TRIMETHYL-2-CYCLOHEXEN-1-YL)-3- BUTEN-2-ONE (3ARS,5ASR,9ASR,9BRS)-3A,6,6,9A- TETRAMETHYLDODECAHYDRONAPHTHO[2,1-B]FURAN (2S,5R)-5-METHYL-2-(2-PROPANYL)CYCLOHEXANONE OXIME 6-HEXYLTETRAHYDRO-2H-PYRAN-2-ONE (+−)-3-(3-ISOPROPYL-1-PHENYL)BUTANAL METHYL 2-((1RS,2RS)-3-OXO-2-PENTYLCYCLOPENTYL)ACETATE (A) + METHYL 2-((1RS,2SR)-3-OXO-2- PENTYLCYCLOPENTYL)ACETATE (B) 1-(2,6,6-TRIMETHYL-1-CYCLOHEX-2-ENYL)PENT-1-EN-3-ONE INDOL 7-PROPYL-2H,4H-1,5-BENZODIOXEPIN-3-ONE ETHYL PRALINE (4-METHYLPHENOXY)ACETALDEHYDE ETHYL TRICYCLO[5.2.1.0.(2,6)]DECANE-2-CARBOXYLATE (+)-(1′S,2S,E)-3,3-DIMETHYL-5-(2′,2′,3′-TRIMETHYL-3′- CYCLOPENTEN-1′-YL)-4-PENTEN-2-OL (2R,4E)-3,3-DIMETHYL-5-[(1R)-2,2,3-TRIMETHYL-3-CYCLOPENTEN- 1-YL]-4-PENTEN-2-OL (A) + (2S,4E)-3,3-DIMETHYL-5-[(1R)-2,2,3- TRIMETHYL-3-CYCLOPENTEN-1-YL]-4-PENTEN-2-OL (B) 8-ISOPROPYL-6-METHYL-BICYCLO[2.2.2]OCT-5-ENE-2- CARBALDEHYDE METHYLNONYLACETALDEHYDE 4-FORMYL-2-METHOXYPHENYL 2-METHYLPROPANOATE (E)-4-DECENAL (+−)-2-ETHYL-4-(2,2,3-TRIMETHYL-3-CYCLOPENTEN-1-YL)-2- BUTEN-1-OL (1R,5R)-4,7,7-TRIMETHYL-6-THIABICYCLO[3.2.1]OCT-3-ENE (A) + (1R,4R,5R)-4,7,7-TRIMETHYL-6-THIABICYCLO[3.2.1]OCTANE (B) (−)-(3R)-3,7-DIMETHYL-1,6-OCTADIEN-3-OL (E)-3-PHENYL-2-PROPENENITRILE 4-METHOXYBENZYL ACETATE (E)-3-METHYL-5-(2,2,3-TRIMETHYL-3-CYCLOPENTEN-1-YL)-4- PENTEN-2-OL ALLYL (3-METHYLBUTOXY)ACETATE (A) + (+−)-ALLYL (2- METHYLBUTOXY)ACETATE (+−)-(2E)-1-(2,6,6-TRIMETHYL-2-CYCLOHEXEN-1-YL)-2-BUTEN-1- ONE (1E)-1-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-1-PENTEN-3-ONE

According to an embodiment, perfume raw materials having a Log T<−4 are chosen in the group consisting of aldehydes, ketones, alcohols, phenols, esters lactones, ethers, epoxydes, nitriles and mixtures thereof.

According to an embodiment, perfume raw materials having a Log T<−4 comprise at least one compound chosen in the group consisting of alcohols, phenols, esters lactones, ethers, epoxydes, nitriles and mixtures thereof, preferably in amount comprised between 20 and 70% by weight based on the total weight of the perfume raw materials having a Log T<−4.

According to an embodiment, perfume raw materials having a Log T<−4 comprise between 20 and 70% by weight of aldehydes, ketones, and mixtures thereof based on the total weight of the perfume raw materials having a Log T<−4.

The remaining perfume raw materials contained in the oil-based core may have therefore a Log T>−4.

Non limiting examples of perfume raw materials having a Log T>−4 are listed in table B below.

TABLE B perfume raw materials having a Log T > −4 Perfume raw materials (Log T > −4) ETHYL 2-METHYLBUTYRATE (E)-3-PHENYL-2-PROPENYL ACETATE (+−)-8-SEC-BUTYLQUINOLINE (A) + (+−)-6-SEC-BUTYLQUINOLINE (+−)-3-(1,3-BENZODIOXOL-5-YL)-2-METHYLPROPANAL VERDYLE PROPIONATE 1-(OCTAHYDRO-2,3,8,8-TETRAMETHYL-2-NAPHTALENYL)-1-ETHANONE METHYL 2-((1RS,2RS)-3-OXO-2-PENTYLCYCLOPENTYL)ACETATE (+−)-(E)-4-METHYL-3-DECEN-5-OL 2,4-DIMETHYL-3-CYCLOHEXENE-1-CARBALDEHYDE 1,3,3-TRIMETHYL-2-OXABICYCLO[2.2.2]OCTANE TETRAHYDRO-4-METHYL-2-(2-METHYL-1-PROPENYL)-2H-PYRAN ALDEHYDE C 12 1-OXA-12-CYCLOHEXADECEN-2-ONE (A) + 1-OXA-13- CYCLOHEXADECEN-2-ONE (B) (+−)-3-(4-ISOPROPYLPHENYL)-2-METHYLPROPANAL ALDEHYDE C 11 LENIQUE (+−)-2,6-DIMETHYL-7-OCTEN-2-OL (+−)-2,6-DIMETHYL-7-OCTEN-2-OL ALLYL 3-CYCLOHEXYLPROPANOATE (Z)-3-HEXENYL ACETATE (2RS,5SR)-5-METHYL-2-(2-PROPANYL)CYCLOHEXANONE (A) + (2RS,5RS)-5-METHYL-2-(2-PROPANYL)CYCLOHEXANONE (B) ALLYL HEPTANOATE (1RS,2RS)-2-(2-METHYL-2-PROPANYL)CYCLOHEXYL ACETATE (A) + (1RS,2SR)-2-(2-METHYL-2-PROPANYL)CYCLOHEXYL ACETATE (B) 1,1-DIMETHYL-2-PHENYLETHYL BUTYRATE GERANYL ACETATE (A) + NERYL ACETATE (B) (+−)-1-PHENYLETHYL ACETATE 1,1-DIMETHYL-2-PHENYLETHYL ACETATE 3-METHYL-2-BUTENYL ACETATE ETHYL 3-OXOBUTANOATE (A) <=> (2Z)-ETHYL 3-HYDROXY-2- BUTENOATE (B) 8-P-MENTHANOL 8-P-MENTHANYL ACETATE (A) + 1-P-MENTHANYL ACETATE (B) (+−)-2-(4-METHYL-3-CYCLOHEXEN-1-YL)-2-PROPANYL ACETATE (+−)-2-METHYLBUTYL BUTANOATE 2-{(1S)-1-[(1R)-3,3-DIMETHYLCYCLOHEXYL]ETHOXY}-2-OXOETHYL PROPIONATE 3,5,6-TRIMETHYL-3-CYCLOHEXENE-1-CARBALDEHYDE (A) + 2,4,6- TRIMETHYL-3-CYCLOHEXENE-1-CARBALDEHYDE (B) 2-CYCLOHEXYLETHYL ACETATE ALDEHYDE C 8 ETHYL BUTANOATE (+−)-(3E)-4-(2,6,6-TRIMETHYL-2-CYCLOHEXEN-1-YL)-3-BUTEN-2-ONE (A) + (3E)-4-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-3-BUTEN-2-ONE (B); 1-[(1RS,6SR)-2,2,6-TRIMETHYLCYCLOHEXYL]-3-HEXANOL 1,3,3-TRIMETHYL-2-OXABICYCLO[2.2.2]OCTANE 1,3,3-TRIMETHYL-2-OXABICYCLO[2.2.2]OCTANE ETHYL HEXANOATE UNDECANAL ALDEHYDE C 10 2-PHENYLETHYL ACETATE (1S,2S,4S)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-OL (A) + (1S,2R,4S)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-OL (B) (+−)-3,7-DIMETHYL-3-OCTANOL 1-METHYL-4-(2-PROPANYLIDENE)CYCLOHEXENE (+)-(R)-4-(2-METHOXYPROPAN-2-YL)-1-METHYLCYCLOHEX-1-ENE VERDYL ACETATE (3R)-1-[(1R,6S)-2,2,6-TRIMETHYLCYCLOHEXYL]-3-HEXANOL (A) + (3S)-1- [(1R,6S)-2,2,6-TRIMETHYLCYCLOHEXYL]-3-HEXANOL (B) + (3R)-1- [(1S,6S)-2,2,6-TRIMETHYLCYCLOHEXYL]-3-HEXANOL (C) (+)-(1S,1′R)-2-[1-(3′,3′-DIMETHYL-1′-CYCLOHEXYL)ETHOXY]-2- METHYLPROPYL PROPANOATE

The nature of high impact perfume raw materials having a Log T<−4 and density balancing material having a density greater than 1.07 g/cm³ are described in WO2018115250, the content of which are included by reference.

In a particular embodiment, the hydrophobic solvent has Hansen Solubility Parameters compatible with entrapped perfume oil.

The term “Hansen solubility parameter” is understood refers to a solubility parameter approach proposed by Charles Hansen used to predict polymer solubility and was developed around the basis that the total energy of vaporization of a liquid consists of several individual parts. To calculate the “weighted Hansen solubility parameter” one must combine the effects of (atomic) dispersion forces, (molecular) permanent dipole-permanent dipole forces, and (molecular) hydrogen bonding (electron exchange). The weighted Hansen solubility parameter” is calculated as (δD²+δP²+δH²)^(0.5), wherein δD is the Hansen dispersion value, δP is the Hansen polarizability value, and δH is the Hansen Hydrogen-bonding (“h-bonding”) value. For a more detailed description of the parameters and values, see Charles Hansen, The Three Dimensional Solubility Parameter and Solvent Diffusion Coefficient, Danish Technical Press (Copenhagen, 1967).

Euclidean difference in solubility parameter between a fragrance and a solvent is calculated as (4*(δD_(solvent)−δD_(fragrance))²+(δP_(solvent)−P_(fragrance))²+(δH_(solvent)−δH_(fragrance))²)^(0.5), in which δD_(solvent), δP_(solvent), and δH_(solvent), are the Hansen dispersion value (also referred to in the following as the atomic dispersion force), Hansen polarizability value (also referred to in the following as the dipole moment), and Hansen h-bonding values of the solvent (also referred to in the following as hydrogen bonding), respectively; and δD_(fragrance), δP_(fragrance), and δH_(fragrance) are the Hansen dispersion value, Hansen polarizability value, and Hansen h-bonding values of the fragrance, respectively.

In a particular embodiment, the perfume oil and the hydrophobic solvent have at least two Hansen solubility parameters selected from a first group consisting of: an atomic dispersion force (δD) from 12 to 20, a dipole moment (δP) from 1 to 8, and a hydrogen bonding (δH) from 2.5 to 11.

In a particular embodiment, at least 90% of the perfume oil, preferably at least 95% of the perfume oil, most preferably at least of 98% of the perfume oil has at least two Hansen solubility parameters selected from a first group consisting of: an atomic dispersion force (δD) from 12 to 20, a dipole moment (δP) from 1 to 8, and a hydrogen bonding (δH) from 2.5 to 11.

In a particular embodiment, the perfume oil and the hydrophobic solvent have at least two Hansen solubility parameters selected from a second group consisting of: an atomic dispersion force (δD) from 12 to 20, preferably from 14 to 20, a dipole moment (δP) from 1 to 8, preferably from 1 to 7, and a hydrogen bonding (δH) from 2.5 to 11, preferably from 4 to 11.

In a particular embodiment, the perfume formulation comprises optionally other active ingredients.

An active ingredient is not limited and can be chosen in the group consisting of a cosmetic ingredient, skin caring ingredient, perfume ingredient, flavor ingredient, malodour counteracting ingredient, bactericide ingredient, fungicide ingredient, pharmaceutical or agrochemical ingredient, a sanitizing ingredient, an insect repellent or attractant, and mixtures thereof.

In a particular embodiment, Perfuming formulation 1 as following is excluded from the present invention:

Raw material wt % Romascone ®^(a)) 20 Verdox ™^(b)) 20 Lorysia ®^(c)) 20 3-(4-isopropylphenyl)-2-methylpropanal 20 Salicynile ®^(d)) 20 ^(a))Methyl 2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate, origin: Firmenich SA, Geneva, Switzerland ^(b))2-tert-butyl-1-cyclohexyl acetate, trademark from International Flavors & Fragrances, USA ^(c))4-(1,1-dimethylethyl)-1-cyclohexyl acetate, origin: Firmenich SA, Geneva, Switzerland ^(d))(2Z)-2-phenyl-2-hexenenitrile, origin: Firmenich SA, Geneva, Switzerland

In a particular embodiment, Perfuming formulation 2 as following is excluded from the present invention:

Raw mat % in oil Ethyl 2-methyl-pentanoate 3.20% Eucalyptol 7.80% 2,4-Dimethyl-3-cyclohexene-1-carbaldehyde ¹⁾ 0.75% Aldehyde C10 0.75% Citronellyl Nitrile 4.30% Isobornyl acetate 3.00% Verdox ® ²⁾ 9.80% Citronellyl Acetate 1.30% 2-Methylundecanal 3.00% Diphenyloxide 0.80% Aldehyde C12 1.30% Dicyclopentadiene acetate 9.85% Ionone beta 3.30% Undecalactone gamma 18.75%  Hexyl Salicylate 15.90%  Benzyl Salicylate 16.20%  TOTAL  100% ¹⁾ Origin: Firmenich SA, Swtizwerland ²⁾ 2-tert-butyl-1-cyclohexyl acetate, origin and trademark from IFF, USA

In a particular embodiment, Perfuming formulation 3 as following is excluded from the present invention:

Component % ACÉTATE DE 4-(1,1-DIMÉTHYLÉTHYL)-1- 14.50 CYCLOHEXYLE ¹⁾ LINALOL BJ 10.50 LILIAL ®²⁾ 10.00 ISO E SUPER ³⁾ 10.00 CITRONELLYL NITRILE 9.00 DIPHENYLOXYDE 6.50 ISOBORNYL ACETATE 6.00 BETA IONONE 6.00 TRICYCLO[5.2.1.0~2,6~]DEC-3-EN-8-YL ACETATE (A) + 5.50 TRICYCLO[5.2.1.0~2,6~]DEC-4-EN-8-YL ACETATE (B) ⁴⁾ ETHER MT 4.00 HEDIONE ® ⁵⁾ 4.00 GERANIOL 60 3.00 CITRAL 2.50 ALDEHYDE C 10 2.50 ALLYL HEPTANOATE 2.50 ETHYL METHYL-2-BUTYRATE 1.50 GERANYL ACETATE 1.00 2,4-DIMETHYL-3-CYCLOHEXENE-1-CARBALDEHYDE ⁶⁾ 1.00 ¹⁾ Firmenich SA, Switzerland ²⁾3-(4-tert-butylphenyl)-2-methylpropanal, Givaudan SA, Vernier, Switzerland ³⁾ 1-(octahydro-2,3,8,8-tetramethyl-2-naphtalenyl)-1-ethanone, International Flavors & Fragrances, USA ⁴⁾ Firmenich SA, Switzerland ⁵⁾ Methyl dihydrojasmonate, Firmenich SA, Switzerland ⁶⁾ Firmenich SA, Switzerland

In a particular embodiment, perfume formulation 4 as following is excluded from the present invention:

Ingredient Parts Isopropyl myristate 0.3 (Z)-3-hexen-1-ol butyrate 0.6 Delta damascene 1.0 2,4-Dimethyl-3-cyclohexene- 1.0 1-carbaldehyde Habanolide ® ¹⁾ 3.0 Hedione ® ²⁾ 5.0 Hexyl cinnamic aldehyde 12.0 Iso E Super ®³⁾ 16.0 Verdyl acetate 24.0 Lilial  ®⁴⁾ 37.0 ¹⁾ Trademark from Firmenich; pentadecenolide, origin: Firmenich SA, Geneva, Switzerland ²⁾ Trademark from Firmenich; Methyl-cis-3-oxo-2-pentyl-1-cyclopentane acetate, origin: Firmenich SA, Geneva, Switzerland ³⁾Trademark from IFF; 7-acetyl, 1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl naphthalene ⁴⁾ Trademark from Givaudan; 3-(4-tert-butylphenyl)-2-methylpropanal

In a particular embodiment, perfume formulation 5 as following is excluded from the present invention:

Raw Materials % in oil 2,4-Dimethyl-3 -cyclohexene-1-carbaldehyde 3.30% Allyl Heptanoate 5.50% Allyl amyl glycolate 10.99%  Delta Damascene 1.65% Verdyl acetate 20.30%  Hedione ®¹⁾ 4.95% Iso E Super  ® ²⁾ 16.49%  Ald. Hexylcinnamique 9.89% Ethyl-2-methylvalerate  3.3% Lilial LG 21.98%  Butyrate de Pipol  1.1% Ambrox ®³⁾ 0.55% Total  100% ¹⁾Methyl dihydrojasmonate, Firmenich SA, Geneva, Switzerland ²⁾ 1-(octahydro-2,3,8,8-tetramethyl-2-naphtalenyl)-1-ethanone, International Flavors & Fragrances, USA ³⁾(−)-(8R)-8,12-epoxy-13,14,15,16-tetranorlabdane, Firmenich SA, Geneva, Switzerland

In a particular embodiment, the perfume formulation has a biodegradability of at least 40%, preferably at least 60%, preferably at least 65%, 70%, 75%, 80%, 85%, 90%, 95% or 98% within 60 days according to OECD301F.

In a particular embodiment, the delivery system has a biodegradability of at least 40%, preferably at least 60%, preferably at least 65%, 70%, 75%, 80%, 85%, 90%, 95% or 98% within 60 days according to OECD301F.

Thereby it is understood that the delivery system including all components, such as the biodegradable carrier and the perfume formulation, have a biodegradability of at least 40%, preferably at least 60%, preferably at least 65%, 70%, 75%, 80%, 85%, 90%, 95% or 98% within 60 days according to OECD301F.

In a particular embodiment, the delivery system has a stability or chemical stability of not more than 40%, preferably not more than 35%, preferably more than 30%, The stability or chemical stability of the delivery system being determined as not more than 40%, preferably not more than 35%, preferably not more than 30%, of the perfume leaking out of the microcapsules when incorporated in a consumer product for a particular storage time and temperature, with the microcapsules being stable after 15 days storage at 37° C., more preferably after 30 days storage at 37° C. preferably in fabric softeners, liquid detergents, body washes, deodorants or antiperspirants, for at least 2 weeks storage at 40° C. in body lotions, shampoos or hair conditioners.

Furthermore, the delivery system show a rubbing effect detectable on fresh samples, and preferably after 15 days of storage in application at 37° C., even more preferably after 30 days at 37° C.

The delivery system of the present invention can be used in combination with active ingredients.

An object of the invention is therefore a composition comprising:

-   -   (i) the delivery system as defined above;     -   (ii) an active ingredient, preferably chosen in the group         consisting of a cosmetic ingredient, skin caring ingredient,         perfume ingredient, flavor ingredient, malodour counteracting         ingredient, bactericide ingredient, fungicide ingredient,         pharmaceutical or agrochemical ingredient, a sanitizing         ingredient, an insect repellent or attractant, and mixtures         thereof.

The delivery system of the present invention can also be added in different perfumed consumer products

In particular, the present invention relates to a perfuming composition comprising

-   -   the delivery system as described herein above and     -   optionally, a free perfume oil.

Preferably, the perfuming composition according to the invention comprises between 0.1 and 30% by weight of the delivery system as defined above.

By “free perfume” it is herein understood a perfume or perfume oil which is comprised in the perfuming composition and not entrapped in a delivery system.

In a particular embodiment, the total amount of the delivery system is 0.05 to 5 wt. % (based on the total weight of the perfuming composition) and the total amount of the free perfume oil is 0.05 to 5 wt. % (based on the total weight of the perfuming composition).

In a particular embodiment, the total perfume oil of the perfume formulation entrapped in the delivery system and total free perfume oil are present in the perfuming composition in a weight ratio of 1:20 to 20:1, preferably 10:1 to 1:10.

The perfuming composition can further comprise at least one perfuming co-ingredient and, optionally a perfumery adjuvant.

By “perfuming co-ingredient” it is herein understood a compound, which is used in a perfuming preparation or a composition to impart a hedonic effect and which is not a microcapsule as 20 defined above. In other words such a co-ingredient, to be considered as being a perfuming one, must be recognized by a person skilled in the art as being able to impart or modify in a positive or pleasant way the odor of a composition, and not just as having an odor. The nature and type of the perfuming co-ingredients present in the perfuming composition do not warrant a more detailed description here, which in any case would not be exhaustive, the skilled person being 25 able to select them on the basis of his general knowledge and according to the intended use or application and the desired organoleptic effect. In general terms, these perfuming co-ingredients belong to chemical classes as varied as alcohols, lactones, aldehydes, ketones, esters, ethers, acetates, nitriles, terpenoids, nitrogenous or sulphurous heterocyclic compounds and essential oils, and said perfuming co-ingredients can be of natural or synthetic origin. Many of these co-30 ingredients are in any case listed in reference texts such as the book by S. Arctander, Perfume and Flavor Chemicals, 1969, Montclair, N.J., USA, or its more recent versions, or in other works of a similar nature, as well as in the abundant patent literature in the field of perfumery. It is also understood that said co-ingredients may also be compounds known to release in a controlled manner various types of perfuming compounds.

By “perfumery adjuvant” it is herein understood an ingredient capable of imparting additional 5 added benefit such as a color, a particular light resistance, chemical stability, etc. A detailed description of the nature and type of adjuvant commonly used in perfuming bases cannot be exhaustive, but it has to be mentioned that said ingredients are well known to a person skilled in the art.

According to an embodiment, the delivery system of the invention (first type of delivery system) can be used in combination with a second type of delivery system. Thus, according to a particular embodiment, the perfuming composition comprises:

-   -   the delivery system of the present invention as a first type of         delivery system, and     -   a second type of delivery system, wherein the first type of         delivery system and the second type of delivery system differ in         their perfuming formulations and/or carrier material (shell or         matrix) and/or outer coating.

The delivery system of the present invention can advantageously be used in many application fields and used in consumer products.

Therefore, in another aspect, the present invention relates to a perfumed consumer product comprising the delivery system according to the present invention or the perfuming composition according to the present invention.

Delivery systems can be used in liquid form applicable to liquid consumer products as well as in powder form, applicable to powder consumer products.

The consumer products of the invention, can in particular be of used in perfumed consumer products such as product belonging to fine fragrance or “functional” perfumery. Functional perfumery includes in particular personal-care products including hair-care, body cleansing, skin care, hygiene-care as well as home-care products including laundry care and air care.

In particular a liquid consumer product comprising:

-   -   from 2 to 65% by weight, relative to the total weight of the         consumer product, of at least one surfactant;     -   water or a water-miscible hydrophilic organic solvent; and     -   a perfuming composition or delivery system as defined herein         above.

Also a powder consumer product comprising

-   -   from 2 to 65% by weight, relative to the total weight of the         consumer product, of at least one surfactant; and     -   a perfuming composition or delivery system as defined herein         above.

For the sake of clarity, it has to be mentioned that, by “perfumed consumer product” it is meant a consumer product which is expected to deliver among different benefits a perfuming effect to the surface to which it is applied (e.g. skin, hair, textile, paper, or home surface) or in the air (air-freshener, deodorizer etc). In other words, a perfumed consumer product according to the invention is a manufactured product which comprises a functional formulation also referred to as “base”, together with benefit agents, among which an effective amount of microcapsules according to the invention.

The nature and type of the other constituents of the perfumed consumer product do not warrant a more detailed description here, which in any case would not be exhaustive, the skilled person being able to select them on the basis of his general knowledge and according to the nature and the desired effect of said product. Base formulations of consumer products in which the microcapsules of the invention can be incorporated can be found in the abundant literature relative to such products. These formulations do not warrant a detailed description here which would in any case not be exhaustive. The person skilled in the art of formulating such consumer products is perfectly able to select the suitable components on the basis of his general knowledge and of the available literature.

Non-limiting examples of suitable perfumed consumer products can be a fine perfume, a splash or eau de perfume, a cologne, a shave or after-shave lotion, a liquid or solid detergent, a mono or multi chamber unidose detergent, a fabric softener, a fabric refresher, liquid or solid scent-boosters (PEG/urea or salts), a dryer sheet, an ironing water, a paper, a bleach, a carpet cleaners, curtain-care products, a shampoo, a coloring preparation, a color care product, a hair shaping product, a dental care product, a disinfectant, an intimate care product, a hair spray, a hair conditioning product, a vanishing cream, a deodorant or antiperspirant, hair remover, tanning or sun product, nail products, skin cleansing, a makeup, a perfumed soap, shower or bath mousse, oil or gel, or a foot/hand care products, a hygiene product, an air freshener, a “ready to use” powdered air freshener, a mold remover, furnisher care, wipe, a dish detergent or hard-surface detergent, a leather care product, a car care product.

In a particular embodiment, the perfumed consumer product is a liquid or solid detergent, a fabric softener, liquid or solid scent-boosters (e.g. using PEG/urea or salts), a shampoo, a shower gel, a hair conditioning product (e.g. leave-on or rinse-off), a deodorant or antiperspirant.

In a particular embodiment, the consumer product comprises:

-   -   a personal care active base, and     -   the delivery system as defined above or the perfuming         composition as defined above, wherein the consumer product is in         the form of a personal care composition.

Personal care active base in which the delivery system of the invention can be incorporated can be found in the abundant literature relative to such products. These formulations do not warrant a detailed description here which would in any case not be exhaustive. The person skilled in the art of formulating such consumer products is perfectly able to select the suitable components on the basis of his general knowledge and of the available literature.

The personal care composition is preferably chosen in the group consisting of a hair-care product (e.g. a shampoo, hair conditioner, a colouring preparation or a hair spray), a cosmetic preparation (e.g. a vanishing cream, body lotion or a deodorant or antiperspirant), a skin-care product (e.g. a perfumed soap, shower or bath mousse, body wash, oil or gel, bath salts, or a hygiene product), oral care product (toothpaste or mouthwash composition) or a fine fragrance product (e.g. Eau de Toilette—EdT).

In a particular embodiment, the consumer product comprises:

-   -   a home care or a fabric care active base, and     -   the delivery system as defined above or the perfuming         composition as defined above,         wherein the consumer product is in the form of a home care or a         fabric care composition.

Home care or fabric care bases in which the delivery system of the invention can be incorporated can be found in the abundant literature relative to such products. These formulations do not warrant a detailed description here which would in any case not be exhaustive. The person skilled in the art of formulating such consumer products is perfectly able to select the suitable components on the basis of his general knowledge and of the available literature.

The home or fabric care composition is preferably chosen in the group consisting fabric softener, liquid detergent, powder detergent, liquid scent booster solid scent booster.

Fabric Softener

An object of the invention is a consumer product in the form of a fabric softener composition comprising:

-   -   a fabric softener active base; preferably chosen in the group         consisting of dialkyl quaternary ammonium salts, dialkyl ester         quaternary ammonium salts (esterquats), Hamburg esterquat (HEQ),         TEAQ (triethanolamine quat), silicones, cationic guars and         mixtures thereof, preferably in an amount comprised between 85         and 99.95% by weight based on the total weight of the         composition,     -   the delivery system as defined above, preferably in an amount         comprised between 0.05 to 15 wt %, more preferably between 0.1         and 5 wt % by weight based on the total weight of the         composition.

Liquid Detergent

An object of the invention is a consumer product in the form of a liquid detergent composition comprising:

-   -   a liquid detergent active base; preferably chosen in the group         consisting of anionic surfactant such as alkylbenzenesulfonate         (ABS), secondary alkyl sulfonate (SAS), primary alcohol sulfate         (PAS), lauryl ether sulfate (LES), methyl ester sulfonate (MES)         and nonionic surfactant such as alkyl amines, alkanolamide,         fatty alcohol poly(ethylene glycol) ether, fatty alcohol         ethoxylate (FAE), ethylene oxide (EO) and propylene oxide (PO)         copolymers, amine oxydes, alkyl polyglucosides, alkyl         polyglucosamides, preferably in an amount comprised between 85         and 99.95% by weight based on the total weight of the         composition,     -   the delivery system as defined above, preferably in an amount         comprised between 0.05 to 15 wt %, more preferably between 0.1         and 5 wt % by weight based on the total weight of the         composition.

Solid Detergent

An object of the invention is a consumer product in the form of a solid detergent composition comprising:

-   -   a solid detergent active base; preferably chosen in the group         consisting of anionic surfactant such as alkylbenzenesulfonate         (ABS), secondary alkyl sulfonate (SAS), primary alcohol sulfate         (PAS), lauryl ether sulfate (LES), methyl ester sulfonate (MES)         and nonionic surfactant such as alkyl amines, alkanolamide,         fatty alcohol poly(ethylene glycol) ether, fatty alcohol         ethoxylate (FAE), ethylene oxide (EO) and propylene oxide (PO)         copolymers, amine oxydes, alkyl polyglucosides, alkyl         polyglucosamides, preferably in an amount comprised between 85         and 99.95% by weight based on the total weight of the         composition,     -   the delivery system as defined above, preferably in an amount         comprised between 0.05 to 15 wt %, more preferably between 0.1         and 5 wt % by weight based on the total weight of the         composition.

Solid Scent Booster

An object of the invention is a consumer product in the form of a solid scent booster comprising:

-   -   a solid carrier, preferably chosen in the group consisting of         urea, sodium chloride, sodium sulphate, sodium acetate, zeolite,         sodium carbonate, sodium bicarbonate, clay, talc, calcium         carbonate, magnesium sulfate, gypsum, calcium sulfate, magnesium         oxide, zinc oxide, titanium dioxide, calcium chloride, potassium         chloride, magnesium chloride, zinc chloride, saccharides such as         sucrose, mono-, di-, and polysaccharides and derivatives such as         starch, cellulose, methyl cellulose, ethyl cellulose, propyl         cellulose, polyols/sugar alcohols such as sorbitol, maltitol,         xylitol, erythritol, and isomalt, PEG, PVP, citric acid or any         water soluble solid acid, fatty alcohols or fatty acids and         mixtures thereof.     -   the delivery system as defined above, in a powdered form,         preferably in an amount comprised between 0.05 to 15 wt %, more         preferably between 0.1 and 5 wt % by weight based on the total         weight of the composition.

Liquid Scent Booster

An object of the invention is a consumer product in the form of a liquid scent booster comprising:

-   -   an aqueous phase,     -   a surfactant system essentially consisting of one or more than         one nonionic surfactant, wherein the surfactant system has a         mean HLB between 10 and 14, preferably chosen in the group         consisting of ethoxylated aliphatic alcohols, POE/PPG         (polyoxyethylene and polyoxypropylene) ethers, mono and         polyglyceryl esters, sucrose ester compounds, polyoxyethylene         hydroxylesters, alkyl polyglucosides, amine oxides and         combinations thereof;     -   a linker chosen in the group consisting of alcohols, salts and         esters of carboxylic acids, salts and esters of hydroxyl         carboxylic acids, fatty acids, fatty acid salts, glycerol fatty         acids, surfactant having an HLB less than 10 and mixtures         thereof, and     -   the delivery system as defined above, in the form of a slurry,         preferably in an amount comprised between 0.05 to 15 wt %, more         preferably between 0.1 and 5 wt % by weight based on the total         weight of the composition.

Shampoo/Shower Gel

An object of the invention is a consumer product in the form of a shampoo or a shower gel composition comprising:

-   -   a shampoo or a shower gel active base; preferably chosen in the         group consisting of sodium alkylether sulfate, ammonium         alkylether sulfates, alkylamphoacetate, cocamidopropyl betaine,         cocamide MEA, alkylglucosides and aminoacid based surfactants         and mixtures thereof, preferably in an amount comprised between         85 and 99.95% by weight based on the total weight of the         composition,     -   the delivery system as defined above, preferably in an amount         comprised between 0.05 to 15 wt %, more preferably between 0.1         and 5 wt % by weight based on the total weight of the         composition.

Rinse-Off Conditioner

An object of the invention is a consumer product in the form of a rinse-off conditioner composition comprising:

-   -   a rinse-off conditioner active base; preferably chosen in the         group consisting of cetyltrimonium chloride, stearyl trimonium         chloride, benzalkonium chloride, behentrimonium chloride and         mixture thereof, preferably in an amount comprised between 85         and 99.95% by weight based on the total weight of the         composition,     -   the delivery system as defined above, preferably in an amount         comprised between 0.05 to 15 wt %, more preferably between 0.1         and 5 wt % by weight based on the total weight of the         composition.

Perfuming Composition

According to a particular embodiment, the consumer product is in the form of a perfuming composition comprising:

-   -   0.1 to 30%, preferably 0.1 to 20% of microcapsules as defined         previously,     -   0 to 40%, preferably 3-40% of perfume, and     -   20-90, preferably 40-90% of ethanol, by weight based on the         total weight of the perfuming composition.

The invention will now be further described by way of examples. It will be appreciated that the invention as claimed is not intended to be limited in any way by these examples

EXAMPLES General Protocol for Preparing Microcapsules Protocol 1

Aqueous solutions of 10% wt. pork gelatine (A), and 10% wt. gum Arabic (B) are prepared separately. The fragrance (Perfume A, B, C, D) to be encapsulated is provided (C). In a vessel at 40° C., the solution (A) and the solution (B) are added to warm demineralised water under mechanical shear. pH is adjusted to 4.45 using HCl 1M. The mixture is maintained at 40° C. during 15 min. The solution (C) is slowly added to the mixture and emulsified/homogenised by mechanical shear forces (impeller, disperser, turbine etc. . . . ) at a given rate to reach the desired average droplet size. Mechanical shear is maintained at the same rate and the solution is then maintain at 40° C. while stirring for 30-60 min. After a duration between 30 to 240 min, the mixture is cooled down to 10° C. at a controlled rate between 0.2 and 0.3° C.min⁻¹. The stirring speed is slightly decreased, and a cross-linking agent (glutaraldehyde aq.50% wt. Supplied by Sigma-Aldrich) is finally added to the mixture. The capsule suspension is mixed during 4 to 10 hours at 20-25° C. to allow a complete reaction. The result is an aqueous suspension of microcapsules.

Protocol 2

Aqueous solutions of 10% wt. pork gelatine (A), and 10% wt. gum Arabic (B) are prepared separately. The fragrance (Perfume A, B, C, D) to be encapsulated is provided (C). In a vessel at 40° C., the solution (A) and the solution (B) are added to warm demineralised water under mechanical shear. The solution (C) is slowly added to the mixture and emulsified/homogenised by mechanical shear forces (impeller, disperser, turbine etc. . . . ) at a given rate to reach the desired average droplet size. pH is adjusted to 4.45 using HCl 1M. The mixture is kept at 40° C. during 15 min. Mechanical shear is maintained at the same rate and the solution is then subjected to a thermal treatment at 50-90° C. After a duration between 30 to 240 min, the mixture is cooled down to 10° C. at a controlled rate between 0.2 and 0.3° C.min⁻¹. The stirring speed is slightly decreased, and a cross-linking agent (glutaraldehyde aq.50% wt. Supplied by Sigma-Aldrich) is finally added to the mixture. The capsule suspension is mixed during 4 to 10 hours at 20-25° C. to allow a complete reaction. The result is an aqueous suspension of microcapsules.

Protocol 3

An aqueous solution of 10% wt. pork gelatine (A) is prepared separately. A fragrance (Perfume A, B, C, D) to be encapsulated is provided (B). Gum Arabic is dissolved in demineralised water to form the aqueous phase. The mixture is stirred until complete solubilisation and warmed at 40° C. Solution (B) is dispersed in the aqueous phase and emulsified by mechanical shear, static mixer, rotor-stator or rotor-rotor to obtain the desired particle size. Solution (A) is then added to the mixture under continued mechanical shear, the pH is adjusted to 4.45 using HCl 1M and maintained as such during 10 min. Mechanical shear is maintained at the same rate and the solution is then subjected to a thermal treatment at 50-90° C. After a duration between 30 to 240 min, the mixture is cooled down to 10° C. at a controlled rate between 0.2 and 0.3° C.min⁻¹. The stirring speed is slightly decreased, and a cross-linking agent (glutaraldehyde aq.50% wt. Supplied by Sigma-Aldrich) is finally added to the mixture. The capsule suspension is mixed during 4 to 10 hours at 20-25° C. to allow a complete reaction. The result is an aqueous suspension or slurry of microcapsules.

TABLE 1 Perfume oil A % in Log Ingredient formula Log P ODT Group δD δP δH (+−)-ETHYL 2-  2.2% <3 >−4 12-20 1-8 2.5-11 METHYLBUTANOATE 2-PHENYLETHYL ACETATE  2.4% <3 >−4 3 12-20 1-8 2.5-11 1-METHOXY-4-METHYLBENZENE  0.5% <3 >−4 12-20 1-8 2.5-11 HEXYL ACETATE 11.70%  <3 >−4 12-20 1-8 2.5-11 TRICYCLO[5.2.1.0~2,6~]DEC-3-EN- 28.5% <3 >−4 5 12-20 1-8 2.5-11 8-YL ACETATE (A) + TRICYCLO[5.2.1.0~2,6~]DEC-4-EN- 8-YL ACETATE (B) (1RS,2RS)-2,4-DIMETHYL-3- 3.15% <3 >−4 1 12-20 1-8 2.5-11 CYCLOHEXENE-1- CARBALDEHYDE (A) + (1 RS,2SR)- 2,4-DIMETHYL-3-CYCLOHEXENE- 1-CARBALDEHYDE (B) METHYL 2-((1RS,2RS)-3-OXO-2-  1.0% <3 >−4 2 12-20 1-8 2.5-11 PENTYLCYCLOPENTYL)ACETATE (+−)-2,6-DIMETHYL-5-HEPTENAL  0.1% 3-3.5 >−4 12-20 1-8 2.5-11 (+−)-2,6-DIMETHYL-7-OCTEN-2-OL  9.5% 3-3.5 >−4 12-20 1-8 2.5-11 3,7-DIMETHYL-2,6-OCTADIEN-1-OL  1.9% 3-3.5 >−4 12-20 1-8 2.5-11 (2RS,4SR)-4-METHYL-2-(2- 0.75% >3.5 >−4 1 12-20 1-8 2.5-11 METHYL-1-PROPEN-1- YL)TETRAHYDRO-2H-PYRAN (A) + (2RS,4RS)-4-METHYL-2-(2- METHYL-1-PROPEN-1- YL)TETRAHYDRO-2H-PYRAN (B) 3-(4,4-DIMETHYL-1- 0.25% >3.5 >−4 12-20 1-8 2.5-11 CYCLOHEXEN-1-YL)PROPANAL 1,1′-OXYDIBENZENE 2.35% >3.5 >−4 3 >20 1-8 2.5-11 (+−)-(E)-4-METHYL-3-DECEN-5-OL 4.75% >3.5 >−4 12-20 1-8 2.5-11 (2E)-1-[(1RS,2SR)-2,6,6- 1.45% >3.5 <−4 3 12-20 1-8 2.5-11 TRIMETHYL-3-CYCLOHEXEN-1- YL]-2-BUTEN-1-ONE (+−)-1,5-DIMETHYL-1-VINYL-4- 2.85% >3.5 >−4 12-20 1-8 2.5-11 HEXENYL ACETATE (3E)-4-(2,6,6-TRIMETHYL-1- 0.40% >3.5 <−4 3 12-20 1-8 2.5-11 CYCLOHEXEN-1-YL)-3-BUTEN-2- ONE 2-METHYLBUTYL SALICYLATE (A) + 3.80% >3.5 >−4 3 12-20 1-8 2.5-11 PENTYL SALICYLATE (B) (+−)-2-METHYLUNDECANAL 13.90%  >3.5 <-4 12-20 1-8 2.5-11 HEXYL 2-HYDROXYBENZOATE 8.55% >3.5 >-4 3 12-20 1-8 2.5-11 Total  100% Log P > 3 * 50.6% Log P > 3.5 * 39.1% Log T < −4 * 15.8% Group 1-6* 52.4% Group 3-6 * 47.5% HSP  100% * excluding hydrophobic solvent

TABLE 2 Variations of Perfume oil A with more hydrophobic and density adjuster solvents Perfume A A1 A2 Parts Perfume A 97%  70% 50% METHYL 3% 15% 25% DIHYDROABIETATE (A) + METHYL ABIETATE (B) + METHYL DEHYDROABIETATE (C) + METHYL TETRAHYDROABIETATE (D) CYCLOHEXYL SALICYLATE 0% 15% 25%

TABLE 3 Perfume oil B % in Log Ingredient formula Log P ODT Group δD δP δH (Z)-3-HEXEN-1-OL 0.20% <3 >−4 12-20 1-8 >11 (2-METHOXYETHYL)BENZENE 1.40% <3 >−4 12-20 1-8 2.5-11 TRICYCLO[5.2.1.0~2,6~]DEC-3-EN-8-YL 30.00%  <3 >−4 5 12-20 1-8 2.5-11 ACETATE (A) + TRICYCLO[5.2.1.0~2,6~]DEC-4- EN-8-YL ACETATE (B) (+−)-2,6-DIMETHYL-5-HEPTENAL 0.75% 3-3.5 >−4 12-20 1-8 2.5-11 1,3,3-TRIMETHYL-2- 3.20% 3-3.5 >−4 5 12-20 1-8 2.5-11 OXABICYCLO[2.2.2]OCTANE (+−)-4-METHYLENE-2-PHENYLTETRAHYDRO- 1.30% 3-3.5 <−4 3 12-20 1-8 2.5-11 2H-PYRAN (A) + (+−)-4-METHYL-6-PHENYL-3,6- DIHYDRO-2H-PYRAN (B) + (+−)-4-METHYL-2- PHENYL-3,6-DIHYDRO-2H-PYRAN (C) .ALPHA.-DIHYDROTERPINEOL (A) + .BETA.- 9.45% 3-3.5 >−4 1 12-20 1-8 2.5-11 DIHYDROTERPINEOL (B) (2RS,4SR)-4-METHYL-2-(2-METHYL-1- 5.50% >3.5 >−4 1 12-20 1-8 2.5-11 PROPEN-1-YL)TETRAHYDRO-2H-PYRAN (A) + (2RS,4RS)-4-METHYL-2-(2-METHYL-1- PROPEN-1-YL)TETRAHYDRO-2H-PYRAN (B) (+−)-3,7-DIMETHYL-1-OCTANOL 0.20% >3.5 >−4 12-20 1-8 2.5-11 2-UNDECANONE 5.50% >3.5 >−4 12-20 1-8 2.5-11 2-METHOXY-3-(4-METHYLPENTYL)PYRAZINE 0.10% >3.5 <−4 12-20 1-8 2.5-11 (+−)-3-(3-ISOPROPYL-1-PHENYL)BUTANAL 1.30% >3.5 <−4 3 12-20 1-8 2.5-11 3-(4-ETHYLPHENYL)-2,2- 2.85% >3.5 >−4 3 12-20 1-8 2.5-11 DIMETHYLPROPANAL (A) + 3-(2- ETHYLPHENYL)-2,2-DIMETHYLPROPANAL (B) 10-UNDECENAL (A) + (9E)-9-UNDECENAL (B) + 2.85% >3.5 <−4 12-20 1-8 2.5-11 (9Z)-9-UNDECENAL (C) (+−)-(E)-4-METHYL-3-DECEN-5-OL 13.60%  >3.5 >−4 12-20 1-8 2.5-11 (2E)-1-[(1RS,2SR)-2,6,6-TRIMETHYL-3- 0.60% >3.5 <−4 3 12-20 1-8 2.5-11 CYCLOHEXEN-1-YL]-2-BUTEN-1-ONE 8-ISOPROPYL-6-METHYL-BICYCLO[2.2.2]OCT- 0.10% >3.5 <−4 5 12-20 1-8 2.5-11 5-ENE-2-CARBALDEHYDE 1-(5,5-DIMETHYL-1-CYCLOHEXEN-1-YL)-4- 1.30% >3.5 <−4 3 12-20 1-8 2.5-11 PENTEN-1-ONE (+−)-2-METHYLUNDECANAL 13.60%  >3.5 <−4 12-20 1-8 2.5-11 (+−)-2-(4-METHYL-3-CYCLOHEXEN-1-YL)-2- 0.10% >3.5 <−4 1 12-20 1-8 2.5-11 PROPANETHIOL (−)-(3AR,5AS,9AS,9BR)-3A,6,6,9A- 0.60% >3.5 <−4 4 12-20 1-8 2.5-11 TETRAMETHYLDODECAHYDRONAPHTHO[2,1- B]FURAN (2Z)-1,1-DIETHOXY-3,7-DIMETHYL-2,6- 4.05% >3.5 >−4 12-20 1-8 2.5-11 OCTADIENE (A) + (2E)-1,1-DIETHOXY-3,7- DIMETHYL-2,6-OCTADIENE (B) CLEARWOOD ® 1.45% >3.5 <−4 5 12-20 1-8 2.5-11 TOTAL  100% Log P > 3: 68.4% Log P > 3.5 53.7% Log T < −4 23.3% Group 1-6 57.8% Group 3-6 42.7% HSP  100%

TABLE 4 Variations of Perfume oil B with more hydrophobic and density adjuster solvent Perfume B B1 B2 Parts Perfume B 100%   75% 50% Phenylethyl Phenylacetate 0%  2.5%  5% Cyclohexyl salicylate 0% 22.5% 45%

TABLE 5 Perfume oil C % in Log Ingredient formula Log P ODT Group δD δP δH (Z)-3-HEXENYL ACETATE 1.15% <3 >−4 12-20 1-8 2.5-11 (1RS,2RS)-2,4-DIMETHYL-3- 5.70% <3 >−4 1 12-20 1-8 2.5-11 CYCLOHEXENE-1- CARBALDEHYDE (A) + (1RS,2SR)- 2,4-DIMETHYL-3-CYCLOHEXENE- 1-CARBALDEHYDE (B) METHYL 2-((1RS,2RS)-3-OXO-2- 2.60% <3 >−4 2 12-20 1-8 2.5-11 PENTYLCYCLOPENTYL)ACETATE (+−)-5-HEPTYLDIHYDRO-2(3H)- 8.00% 3-3.5 <−4 12-20 1-8 2.5-11 FURANONE 1,3,3-TRIMETHYL-2- 6.10% 3-3.5 >−4 5 12-20 1-8 2.5-11 OXABICYCLO[2.2.2]OCTANE 2-METHOXYNAPHTHALENE 8.00% 3-3.5 <−4 4 >20 1-8 2.5-11 3,5,6-TRIMETHYL-3- 1.05% 3-3.5 >−4 1 12-20 1-8 2.5-11 CYCLOHEXENE-1- CARBALDEHYDE (A) + 2,4,6- TRIMETHYL-3-CYCLOHEXENE-1 - CARBALDEHYDE (B) (Z)-3-HEXENYL ISOBUTYRATE 0.65% >3.5 >−4 12-20 1-8 2.5-11 3,7-DIMETHYL-2,6- 12.40% >3.5 >−4 12-20 1-8 2.5-11 NONADIENENITRILE (A) + 3,7- DIMETHYL-3,6- NONADIENENITRILE (B) (1R,2R)-1,7,7-TRIMETHYL- 12.75% >3.5 >−4 5 12-20 1-8 2.5-11 BICYCLO[2.2.1]HEPT-2-YL ACETATE 10-UNDECENAL (A) + (9E)-9- 1.35% >3.5 <−4 12-20 1-8 2.5-11 UNDECENAL (B) + (9Z)-9- UNDECENAL (C) (−)-(1S)-2,6,6-TRIMETHYL- 3.25% >3.5 >−4 12-20 <1 2.5-11 BICYCLO[3.1.1]HEPT-2-ENE (+−)-1,5-DIMETHYL-1-VINYL-4- 12.40% >3.5 >−4 12-20 1-8 2.5-11 HEXENYL ACETATE 1-(5,5-DIMETHYL-1- 1.60% >3.5 <−4 3 12-20 1-8 2.5-11 CYCLOHEXEN-1-YL)-4-PENTEN-1- ONE 3,7-DIMETHYL-6-OCTENYL 4.75% >3.5 >−4 12-20 1-8 2.5-11 ACETATE (+−)-2-METHYLUNDECANAL 8.00% >3.5 <−4 12-20 1-8 2.5-11 (+−)-2-(4-METHYL-3- 0.10% >3.5 <−4 1 12-20 1-8 2.5-11 CYCLOHEXEN-1-YL)-2- PROPANETHIOL (+−)-(3E)-3-METHYL-4-(2,6,6- 0.65% >3.5 <−4 3 12-20 1-8 2.5-11 TRIMETHYL-2-CYCLOHEXEN-1- YL)-3-BUTEN-2-ONE (A) + (+−)- (1E)-1-(2,6,6-TRIMETHYL-2- CYCLOHEXEN-1-YL)-1-PENTEN-3- ONE (B) 1-OXA-12-CYCLOHEXADECEN-2- 4.75% >3.5 >−4 6 12-20 1-8 2.5-11 ONE (A) + 1-OXA-13- CYCLOHEXADECEN-2-ONE (B) OXACYCLOHEXADECAN-2-ONE 4.75% >3.5 >−4 6 12-20 1-8 2.5-11 TOTAL 100.00% Log P > 3: 90.6% Log P > 3.5 67.4% Log T < −4 28.6% Group 1-6 49.7% Group 3-6 39.9% HSP  100%

TABLE 6 Variations of Perfume oil C with more hydrophobic and density adjuster solvent Perfume C C1 C2 Parts Perfume C 100% 80% 55% Benzyl salicylate  0% 20% 45%

TABLE 7 Perfume oil D % in Log Ingredient formula Log P ODT Group δD δP δH OCTANAL 2.50% <3 >−4 12-20 1-8 2.5-11 1,3,3-TRIMETHYL-2- 2.10% 3-3.5 >−4 5 12-20 1-8 2.5-11 OXABICYCLO[2.2.2]OCTANE 2-METHOXYNAPHTHALENE 10.00%  3-3.5 <−4 4 >20 1-8 2.5-11 (+−)-4-METHYLENE-2-PHENYLTETRAHYDRO- 3.00% 3-3.5 <−4 3 12-20 1-8 2.5-11 2H-PYRAN (A) + (+−)-4-METHYL-6-PHENYL-3,6- DIHYDRO-2H-PYRAN (B) + (+−)-4-METHYL-2- PHENYL-3,6-DIHYDRO-2H-PYRAN (C) DECANAL 5.00% >3.5 >−4 12-20 1-8 2.5-11 (+−)-3,7-DIMETHYL-6-OCTENAL 30.00%  >3.5 >−4 12-20 1-8 2.5-11 (+)-(3S)-3-[(1R)-4-METHYL-3-CYCLOHEXEN-1- 10.00%  >3.5 >−4 3 12-20 1-8 2.5-11 YL]BUTANAL (A) + (+)-(3R)-3-[(1R)-4-METHYL- 3-CYCLOHEXEN-1-YL]BUTANAL (1R,2R)-1,7,7-TRIMETHYL- 5.00% >3.5 >−4 5 12-20 1-8 2.5-11 BICYCLO[2.2.1]HEPT-2-YL ACETATE 8-ISOPROPYL-6-METHYL-BICYCLO[2.2.2]OCT- 0.60% >3.5 <−4 5 12-20 1-8 2.5-11 5-ENE-2-CARBALDEHYDE (+−)-2-METHYLUNDECANAL 8.00% >3.5 <−4 12-20 1-8 2.5-11 (−)-(3AR,5AS,9AS,9BR)-3A,6,6,9A- 0.70% >3.5 <−4 4 12-20 1-8 2.5-11 TETRAMETHYLDODECAHYDRONAPHTHO[2,1- B]FURAN (2Z)-1,1-DIETHOXY-3,7-DIMETHYL-2,6- 20.00%  >3.5 >−4 12-20 1-8 2.5-11 OCTADIENE (A) + (2E)-1,1-DIETHOXY-3,7- DIMETHYL-2,6-OCTADIENE (B) (2Z)-2-TRIDECENENITRILE (A) + (3Z)-3- 2.00% >3.5 <−4 12-20 1-8 2.5-11 TRIDECENENITRILE (B) + (3E)-3- TRIDECENENITRILE (C) + (2E)-2- TRIDECENENITRILE (D) PATCHOULI OIL 1.10% >3.5 <−4 5 12-20 1-8 2.5-11 TOTAL  100% Log P > 3: 97.5% Log P > 3.5 82.4% Log T < −4 25.4% Group 1-6 32.5% Group 3-6 32.5% HSP  100%

TABLE 8 Variations of Perfume oil D with more hydrophobic & density adjuster solvent Perfume D D1 D2 Parts Perfume D 100%   75% 50% Phenylethyl Phenylacetate 0%  2.5%  5% Cyclohexyl salicylate 0% 22.5% 45%

Example 1

Preparation of Microcapsules Slurry

Microcapsules A-D have been prepared by using Protocol 3. Similar results have been obtained by using Protocol 1 and 2.

TABLE 9 Microcapsules compositions Components A B C D Water 74.8 74.8 74.8 74.8 Gum arabic¹⁾ 1.1 1.1 1.1 1.1 Gelatine²⁾ 1.1 1.1 1.1 1.1 Perfume³⁾ 22.1 22.1 22.1 22.1 (Perfume A) (Perfume B) (Perfume C) (Perfume D) Lactic acid⁴⁾ 0.5 0.5 0.5 0.5 Glutar- 0.04 0.04 0.04 0.04 aldehyde⁵⁾ Particle size 72 72 72 72 (microns) ¹⁾Nexira ²⁾PB Leiner ³⁾See tables 1, 3, 5 & 7 ⁴⁾Purac Biochem, 90% aqueous solution ⁵⁾Sigma Aldrich, 50% aqueous solution Some of the microcapsules slurries (A, B, C and D) were mixed then with preservatives and thickening polymers (0.5% sodium benzoate and 0.1 to 0.5% xanthan gum). The biodegradability of the shell has been determined by using the OECD301F

Shell Extraction

The slurry is washed in a separating funnel with DI water 3 times. The washed microcapsules are centrifuged for 20 minutes at 5000 RPM. The microcapsules are removed and dried at RT for 2 days. The dried shells have been grinded and splited in erlenmeyers and the perfume extracted with Ethyl Acetate (concentration 5 wt %) and magnetic stirring (1 h; 500 rpm). The shells were filtered under vacuum with a sintered glass funnel. Extraction was done five times. Shell was collected into a crystallizer and dried at 50° C. under vacuum and then crushed with IKA Tube Mill (5 min; 20100 rpm) to get a white powder. Shells were stirred in water for 24 h and recovered by filtration. Shell was dried and crushed again by IKA Tube Mill (5 min; 20100 rpm). Shells were extracted with Ethyl Acetate and magnetic stirring (1 h; 600 rpm), and filtered under vacuum with a sintered glass funnel. Process was repeated five times. Shells were collected into a crystallizer and dried at 50° C. under vacuum. Resulting product was crushed (IKA Tube Mill, 5 min; 20100 rpm). The biodegradability of the shell for samples A-D was greater than 60% after 60 days of test.

Example 2

Liquid Detergent Composition

A sufficient amount of microcapsule slurry A-D of the present invention was dispersed in liquid detergent base described in table 10 to obtain a concentration of encapsulated perfume oil at 0.22%.

TABLE 10 Composition of the liquid detergent formulation Ingredients Concentration [wt %] Sodium C14-17 Alkyl Sec Sulfonate¹⁾ 7 Fatty acids, C12-18 and C18-unsaturated²⁾ 7.5 C12/14 fatty alcohol polyglycol ether with 7 17 mol EO³⁾ Triethanolamine 7.5 Propylene Glycol 11 Citric acid 6.5 Potassium Hydroxyde 9.5 Protease 0.2 Amylase 0.2 Mannanase 0.2 Acrylates/Steareth-20 Methacrylate 6 structuring Crosspolymer⁴⁾ Deionized Water 27.4 ¹⁾Hostapur SAS 60; Origin: Clariant ²⁾Edenor K 12-18; Origin: Cognis ³⁾Genapol LA 070; Origin: Clariant ⁴⁾Aculyn 88; Origin: Dow Chemical

Example 3

Rinse-Off Conditioner

A sufficient amount of microcapsule slurry A-D of the present invention was incorporated at the required dosage (corresponding to an encapsulated perfume oil at 0.5%) in the rinse-off base (see Table 11).

TABLE 11 rinse-off conditioner composition Ingredients Concentration [wt %] A Water deionized 81.8 Behentrimonium Chloride ¹⁾ 2.5 Hydroxyethylcellulose ²⁾ 1.5 B Cetearyl Alcohol ³⁾ 4 Glyceryl Stearate (and) PEG-100 Stearate ⁴⁾ 2 Behentrimonium Methosulfate (and) Cetyl 4 alcohol (and) Butylene Glycol ⁵⁾ Ethoxy (20) Stearyl Alcohol ⁶⁾ 1 C Amodimethicone (and) Trideceth-12 (and) 3 Cetrimonium Chloride ⁷⁾ Chlorhexidine Digluconate ⁸⁾ 0.2 20% aqueous solution D Citric acid 10% aqueous sol. till pH 3.5-4 q.s. TOTAL: 100 ¹⁾ Genamin KDM P, Clariant ²⁾ Tylose H10 Y G4, Shin Etsu ³⁾ Lanette O, BASF ⁴⁾ Arlacel 165-FP-MBAL-PA-(RB), Croda ⁵⁾ Incroquat Behenyl TMS-50-MBAL-PA-(MH) HA4112, Croda ⁶⁾ SP Brij S20 MBAL-PA(RB), Croda ⁷⁾ Xiameter DC MEM-0949 Emulsion, Dow Corning ⁸⁾ Alfa Aesar

Ingredients of Phase A are mixed until a uniform mixture was obtained. Tylose is allowed to completely dissolve. Then the mixture is heated up to 70-75° C. Ingredients of Phase B are combined and melted at 70-75° C. Then ingredients of Phase B are added to Phase A with good agitation and the mixing is continued until cooled down to 60° C. Then, ingredients of Phase C are added while agitating and keeping mixing until the mixture cooled down to 40° C. The pH is adjusted with citric acid solution till pH: 3.5-4.0.

Example 4

Spray-Dried Microcapsules Preparation

Emulsions 1-5 having the following ingredients are prepared.

TABLE 12 Composition of Emulsions 1-5 and composition of granulated powder 1-5 after spray-drying Ingredients Emulsion 1 Emulsion 2 Emulsion 3 Emulsion 4 Emulsion 5 Modified starch ¹⁾ 2.6%  2.6%  2.6%  12.5%  2% Maltodextrin ²⁾ 26.8%   22.8%   19.3%    0% 19.1%   Maltose ³⁾ 0% 0% 0% 7.9% 0% Citric Acid 0% 0% 0%  1% 0% Tripotassium 0% 0% 0% 1.9% 0% Citrate Microcapsules 12.0%   24%  37.0%   8.9% 56.2%   A-D Silica ⁴⁾ 1.1%  1.1%  1.1%   0% 0% Free Perfume 0% 0% 0%  11% 0% Water 57.6%   49.6%   40.1%   56.9%  22.7%   Granule 1 Granule 2 Granule 3 Granule 4 Granule 5 Modified starch ¹⁾ 7.5%  7.4%  7.2%  31.6% 4.9%  Maltodextrin ²⁾ 77.4%   65.5%   53.8%     0% 44.7%   Maltose 0% 0% 0% 20.9% Citric Acid 0% 0% 0%  2.6% 0% Tripotassium 0% 0% 0%  4.9% 0% citrate Encapsulated 0% 0% 0% 28.1% 0% perfume Microcapsules A-D 12.%  24.1%   36.1%    9.8% 48.4%   Silica 3.0 3.0%  2.9%   2.0% 2% Fragrance loading 10.1%   20.1%   30%  35.8% 40.2%   in powder after spray-drying ¹⁾ CapsulTM, Ingredion ²⁾ Maltodextrin 10DE origin: Roquette ³⁾ Maltose, Lehmann & Voss ⁴⁾ Silica, Evonik Components for the polymeric matrix (Maltodextrin and Capsul™, or Capsul™, citric acid and tripotassium citrate) are added in water at 45-50° C. until complete dissolution. For emulsion 4, free perfume C is added to the aqueous phase. Microcapsules slurry is added to the obtained mixture. Then, the resulting mixture is then mixed gently at 25° C. (room temperature). Granulated powder 1-5 are prepared by spray-drying Emulsion A-E using a Sodeva Spray Dryer (Origin France), with an air inlet temperature set to 215° C. and a throughput set to 500 ml per hour. The air outlet temperature is of 105° C. The emulsion before atomization is at ambient temperature.

Example 5

Liquid Scent Booster Composition

A sufficient amount of microcapsule slurry A-D is weighed and mixed in a liquid scent booster to add the equivalent of 0.2% perfume.

TABLE 13 Liquid scent booster composition Amount (% wt) Ingredients 1 2 3 4 5 6 Water 71.20% 89.5%  78.8% 79.4%  70%  70% Propylene glycol 20.30% — — —  20%  20% Polyethylene glycol 4.00%  6% ethers of decyl alcohol¹⁾ Polyethylene glycol 4.00% 4.00% ether of Lauryl Alcohol²⁾ alkyl polyglucoside C8- 8.30%  7.7% C10³⁾ Deceth-3¹⁾ 1.50% Lauryl lactate   1% Lauric acid 1.5% 1.60% Glyceryl Caprylate 3.00% 3.00% Fragrance 3.00% 3.0% 3.00% 3.00% 3.00%   0% ¹⁾Deceth-8; trademark and origin: KLK Oleo ²⁾Laureth-9; ; trademark and origin ³⁾Plantacare 2000UP; trademark and origin: BASF

Different ringing gel compositions are prepared (compositions 1-6) according to the following protocol.

In a first step, the aqueous phase (water), the solvent (propylene glycol) if present and surfactants are mixed together at room temperature under agitation with magnetic stirrer at 300 rpm for 5 min.

In a second step, the linker is dissolved in the hydrophobic active ingredient (fragrance) at room temperature under agitation with magnetic stirrer at 300 rpm. The resulting mixture is mixed for 5 min.

Then, the aqueous phase and the oil phase are mixed together at room temperature for 5 min leading to the formation of a transparent or opalescent ringing gel.

Example 6

Powder Detergent Composition

A sufficient amount of granules 1-5 is weighed and mixed in a powder detergent composition to add the equivalent of 0.2% perfume.

TABLE 14 Powder detergent composition Ingredients Part Anionic (Linear Alkyl Benzene 20% Sulphonates) Nonionics (Alcohol Ethoxylates (5-9  6% ethylene oxide) Builders (zeolites, sodium carbonate) 25% Silicates  6% Sodium Sulphate 35% Others (Enzymes, Polymers, Bleach) 7.5%  Spray-dried granule powder 1-5 0.5% 

Example 7

Concentrated all Purpose Cleaner Composition

A sufficient amount of microcapsule slurry A-D is weighed and mixed in a concentrated all-purpose cleaner composition to add the equivalent of 0.2% perfume.

TABLE 15 concentrated all-purpose cleaner composition Ingredients Amount (% wt) Function Ethoxylated Alcohol (C9- 20 Non-ionic surfactant C11, 8EO) ⁽¹⁾ Sodium Dodecyl Benzene 16 Anionic surfactant Sulfonate ⁽²⁾ Sodium Cumene Sulfonate ⁽³⁾ 8 Hydrotrope Methyl chloro isothiazolinone 0.8% preservative Methyl isothiazolinone 3.3:1 ⁽⁴⁾ Water 55.9 solvent ⁽¹⁾ Neodol 91-8  ®; trademark and origin: Shell Chemical ⁽²⁾ Biosoft D-40 ®; trademark and origin: Stepan Company ⁽³⁾ Stepanate SCS ®; trademark and origin: Stepan Company ⁽⁴⁾ Kathon CG ®; trademark and origin: Dow Chemical Company All ingredients are mixed together and then the mixture was diluted with water to 100%.

Example 8

Solid Scent Booster Composition

A sufficient amount of microcapsules in dried form is weighed and mixed with a solid scent booster composition to add the equivalent of 0.2% perfume.

TABLE 16 Salt-based solid scent booster compositions Ingredients Part Sodium chloride 95 Spray-dried granule powder 1-5 5

TABLE 17 Urea-based solid scent booster compositions Ingredients Part Urea (beads) 86 Spray-dried granule powder 1-5 8 Bentonite 3 Perfume 3

Example 9

Shampoo Composition

A sufficient amount of microcapsule slurry A-D is weighed and mixed in a shampoo composition to add the equivalent of 0.2% perfume.

TABLE 18 Shampoo composition Ingredients Concentration [wt %] A Water deionized 44.4 Polyquaternium-10 ¹⁾ 0.3 Glycerin 85% ²⁾ 1 DMDM Hydantoin ³⁾ 0.2 B Sodium Laureth Sulfate ⁴⁾ 28 Cocamidopropyl Betaine ⁵⁾ 3.2 Disodium Cocoamphodiacetate ⁶⁾ 4 Ethoxy (20) Stearyl Alcohol ⁶⁾ 1 C Sodium Laureth Sulfate ⁴⁾ 3 Glyceryl Laureate ⁷⁾ 0.2 D Water deionized 1 Sodium Methylparaben ⁸⁾ 0.1 E Sodium Chloride 10% aqueous sol. 15 Citric acid 10% aqueous sol. till pH 5.5-6 q.s. Perfume 0.5 TOTAL: 100 ¹⁾ Ucare Polymer JR-400, Noveon ²⁾ Schweizerhall ³⁾ Glydant, Lonza ⁴⁾ Texapon NSO IS, Cognis ⁵⁾ Tego Betain F 50, Evonik ⁶⁾ Amphotensid GB 2009, Zschimmer & Schwarz ⁷⁾ Monomuls 90 L-12, Gruenau ⁸⁾ Nipagin Monosodium, NIPA Polyquaternium-10 is dispersed in water. The remaining ingredients of phase A are mixed separately by addition of one after the other while mixing well after each adjunction. Then this pre-mix is added to the Polyquaternium-10 dispersion and was mixed for 5 min. Then Phase B and the premixed Phase C (heat to melt Monomuls 90L-12 in Texapon NSO IS) are added. The mixture is mixed well. Then, Phase D and Phase E are added while agitating. The pH was adjusted with citric acid solution till pH: 5.5-6.0.

Example 10

Shampoo Composition

A sufficient amount of microcapsule slurry A-D is weighed and mixed in a shampoo composition to add the equivalent of 0.2% perfume.

TABLE 19 Shampoo composition Ingredients Concentration [wt %] A Water deionized 45.97 Tetrasodium EDTA ¹⁾ 0.05 Guar Hydroxypropyltrimonium Chloride ²⁾ 0.05 Polyquaternium-10 ³⁾ 0.075 B NaOH 10% aqueous sol. 0.3 C Ammonium Lauryl Sulfate ⁴⁾ 34 Ammonium Laureth Sulfate ⁵⁾ 9.25 Cocamidopropyl Betaine ⁶⁾ 2 Dimethicone (&) C12-13 Pareth-4 (&) 2.5 C12-13 Pareth-23 (&) Salicylic Acid ⁷⁾ D Cetyl Alcohol ⁸⁾ 1.2 Cocamide MEA ⁹⁾ 1.5 Glycol Distearate ¹⁰⁾ 2 E Methylchloroisothiazolinone & 0.1 Methylisothiazolinone ¹¹⁾ D-Panthenol 75% ¹²⁾ 0.1 Water deionized 0.3 F Sodium Chloride 25% aqueous sol. 0.6 TOTAL: 100 ¹⁾ EDETA B Powder, BASF ²⁾ Jaguar C14 S, Rhodia ³⁾ Ucare Polymer JR-400, Noveon ⁴⁾ Sulfetal LA B-E, Zschimmer & Schwarz ⁵⁾ Zetesol LA, Zschimmer & Schwarz ⁶⁾ Tego Betain F 50, Evonik ⁷⁾ Xiameter MEM-1691, Dow Corning ⁸⁾ Lanette 16, BASF ⁹⁾ Comperlan 100, Cognis ¹⁰⁾ Cutina AGS, Cognis ¹¹⁾ Kathon CG, Rohm & Haas ¹²⁾ D-Panthenol, Roche A premix comprising Guar Hydroxypropyltrimonium Chloride and Polyquaternium-10 are added to water and Tetrasodium EDTA while mixing. When the mixture is homogeneous, NaOH is added. Then, Phase C ingredients are added and the mixture was heat to 75° C. Phase D ingredients are added and mixed till homogeneous. The heating is stopped and temperature of the mixture is decreased to RT. At 45° C., ingredients of Phase E while mixing final viscosity is adjusted with 25% NaCl solution and pH of 5.5-6 is adjusted with 10% NaOH solution.

Example 11

Antiperspirant Spray Anhydrous Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in an antiperspirant spray anhydrous composition to add the equivalent of 0.2% perfume.

TABLE 20 antiperspirant spray anhydrous composition Ingredient Amount (wt %) Cyclomethicone¹⁾ 53.51 Isopropyl miristate 9.04 Silica²⁾ 1.03 Quaternium-18-Hectorite³⁾ 3.36 Aluminium Chlorohydrate⁴⁾ 33.06 ¹⁾Dow Corning ® 345 Fluid; trademark and origin: Dow Corning ²⁾Aerosil ® 200; trademark and origin: Evonik ³⁾Bentone ® 38; trademark and origin: Elementis Specialities ⁴⁾Micro Dry Ultrafine; origin: Reheis Using a high speed stirrer, Silica and Quaternium-18-Hectorite are added to the Isopropyl miristate and Cyclomethicone mixture. Once completely swollen, Aluminium Chlorohydrate is added portion wise under stirring until the mixture was homogeneous and without lumps. The aerosol cans are filled with 25% Suspension of the suspension and 75% of Propane/Butane (2,5 bar).

Example 12

Antiperspirant Spray Emulsion Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in antiperspirant spray emulsion composition to add the equivalent of 0.2% perfume.

antiperspirant spray emulsion composition Ingredient Amount (wt %) Polysorbate 65¹⁾ (Part A) 0.95 Polyglyceryl-2 dipolyhydroxystearate²⁾ 1.05 (Part A) Cetyl PEG/PPG-10/1 Dimethicone³⁾ 2.75 (Part A) Cyclomethicone⁴⁾ (Part A) 16.4 lsopropylisostearate⁵⁾ (Part A) 4.5 Phenoxyethanol⁶⁾ (Part A) 0.5 Ethylhexylglycerin⁷⁾ (Part A) 0.2 C12-15 Alkyl Benzoate⁸⁾ (Part A) 5.65 Silica Silylate⁹⁾ (Part A) 0.1 Sodium Methylparaben¹⁰⁾ (Part B) 0.1 Aluminium Chlorohydrate¹¹⁾ (Part B) 20 Water (Part B) 44.47 Fragrance (Part C) 3.33 ¹⁾Tween 65; trademark and origin: CRODA ²⁾Dehymuls PGPH; trademark and origin: BASF ³⁾Abil EM-90; trademark and origin: BASF ⁴⁾Dow Corning 345 fluid; trademark and origin: Dow Corning ⁵⁾Crodamol ipis; trademark and origin: CRODA ⁶⁾Phenoxyethanol; trademark and origin: LANXESS ⁷⁾Sensiva sc 50; trademark and origin: KRAFT ⁸⁾Tegosoft TN; trademark and origin: Evonik ⁹⁾Aerosil R 812; trademark and origin: Evonik ¹⁰⁾Nipagin mna; trademark and origin: CLARIANT ¹¹⁾Locron L; trademark and origin: CLARIANT The ingredients of Part A and Part B are weighted separately. Ingredients of Part A are heated up to 60° C. and ingredients of Part B are heated to 55° C. Ingredients of Part B are poured small parts while continuous stirring into A. Mixture were stirred well until the room temperature was reached. Then, ingredients of part C are added. The emulsion is mixed and is introduced into the aerosol cans. The propellant is crimped and added. Aerosol filling: 30% Emulsion: 70% Propane/Butane 2,5 bar

Example 13

Deodorant Spray Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in antiperspirant deodorant spray composition to add the equivalent of 0.2% perfume.

TABLE 22 deodorant spray composition Ingredient Amount (wt %) Ethanol 95% 90.65 Triclosan¹⁾ 0.26 Isopropyl miristate 9.09 ¹⁾Irgasan ® DP 300; trademark and origin: BASF All the ingredients according to the sequence of the Table above are mixed and dissolved. Then the aerosol cans are filled, crimp and the propellant is added (Aerosol filling: 40% active solution 60% Propane/Butane 2.5 bar).

Example 14

Antiperspirant Roll-on Emulsion Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in antiperspirant roll-on emulsion composition to add the equivalent of 0.2% perfume.

TABLE 23 antiperspirant roll-on emulsion composition Ingredient Amount (wt %) Steareth-2¹⁾ (Part A) 3.25 Steareth-21²⁾ (Part A) 0.75 PPG-15 Stearyl Ether³⁾ (Part A) 4 WATER deionised (Part B) 51 Aluminum Chlorohydrate 50% 40 aqueous solution⁴⁾ (Part C) Fragrance (Part D) 1 ¹⁾BRIJ 72; origin: ICI ²⁾BRIJ 721; origin: ICI ³⁾ARLAMOL E; origin: UNIQEMA-CRODA ⁴⁾LOCRON L; origin: CLARIAN Part A and B are heated separately to 75° C.; Part A is added to part B under stirring and the mixture is homogenized for 10 minutes. Then, the mixture is cooled down under stirring; and part C is slowly added when the mixture reached 45° C. and part D when the mixture reached at 35° C. while stirring. Then the mixture is cooled down to RT.

Example 15

Antiperspirant Roll-on Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in antiperspirant roll-on composition to add the equivalent of 0.2% perfume.

TABLE 24 antiperspirant roll-on composition Ingredient QUANTITY Water (Part A) 45 Aluminum Chlorohydrate 50% aqueous 20 solution¹⁾ (Part B) Alcohol Denat. (Ethanol 96%) (Part B) 30 Ceteareth-12²⁾ (Part C) 2 Ceteareth-30³⁾ (Part C) 2 Fragrance (Part D) 1 ¹⁾LOCRON L; origin: CLARIANT ²⁾EUMULGIN B-1; origin: BASF ³⁾EUMULGIN B-3; origin: BASF The ingredients of part B are mixed in the vessel then ingredient of part A is added. Then dissolved part C in part A and B. With perfume, 1 part of Cremophor RH40 for 1 part of perfume is added while mixing well

Example 16

Antiperspirant Roll-on Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in antiperspirant roll-on emulsion composition to add the equivalent of 0.2% perfume.

TABLE 25 antiperspirant roll-on emulsion composition Ingredient Amount (wt %) Water (Part A) 50.51 Hydroxyethylcellulose¹⁾ (Part A) 0.71 Ethanol 95% (Part B) 40.40 1,2-Propylene Glycol (Part B) 5.05 Triclosan²⁾ (Part B) 0.30 PEG-40 Hydrogenated castor oil³⁾ (Part C) 3.03 ¹⁾Natrosol ® 250 H; trademark and origin: Ashland ²⁾Irgasan ® DP 300; trademark and origin: BASF ³⁾Cremophor ® RH 40; trademark and origin: BASF Part A is prepared by sprinkling little by little the Hydroxyethylcellulose in the water whilst rapidly stirring with the turbine. Stirring is continued until the Hydroxyethylcellulose is entirely swollen and giving a limpid gel. Then, Part B is poured little by little in Part A whilst continuing stirring until the whole is homogeneous. Part C is added.

Example 17

Deodorant Pump without Alcohol Formulation

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 26 deodorant composition Ingredients Amount (wt %) C12-15 Alkyl 5 Lactate¹⁾ Dimethicone²⁾ 91.6 Cetyl Lactate³⁾ 1 Octyldodecanol⁴⁾ 0.8 Triclosan⁵⁾ 0.1 PERFUME 1.5 ¹⁾Ceraphyl 41; trademark and origin ASHLAND ²⁾DOW CORNING 200 FLUID 0.65 cs; trademark and origin DOW CORNING CORPORATION ³⁾Ceraphyl 28; trademark and origin ASHLAND ⁴⁾Eutanol G; trademark and origin BASF ⁵⁾Irgasan ® DP 300; trademark and origin: BASF All the ingredients are mixed according to the sequence of the table and the mixture is heated slightly to dissolve the Cetyl Lactate.

Example 18

Deodorant Pump with Alcohol Formulation

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 27 deodorant composition Ingredients Amount (wt %) Ethyl Alcohol (Part A) 60 PEG-6 Caprylic/Capric Glycerides¹⁾ (Part A) 2 Water (Part A) 35.6 PEG-40 Hydrogenated Castor Oil²⁾ (Part B) 0.4 PERFUME (Part B) 2 ¹⁾Softigen 767; trademark and origin CRODA ²⁾Cremophor ® RH 40; trademark and origin: BASF Ingredients from Part B are mixed together. Ingredients of Part A are dissolved according to the sequence of the Table and are poured into part B.

Example 19

Deodorant Stick without Alcohol Formulation

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 28 deodorant composition Ingredient Amount (wt %) Stearic acid (Part A) 5.05 1,2-propylene glycol (Part A) 41.87 Sodium hydroxide 20% aqueous solution 4.24 (Part A) Water (Part A) 30.30 Tetrasodium EDTA¹⁾ (Part A) 0.10 Ceteareth-25²⁾ (Part A) 1.52 PPG-3 Myristyl ether³⁾ (Part A) 1.52 1,2-propylene glycol (Part B) 15.14 Triclosan⁴⁾ (Part B) 0.25 ¹⁾Edeta ® B Power; trademark and origin: BASF ²⁾Cremophor ® A25; trademark and origin: BASF ³⁾Tegosoft ® APM; trademark and origin: Evonik ⁴⁾Irgasan ® DP 300; trademark and origin: BASF All the components of Part A are weighted and heated up to 70-75° C. Ceteareth-25 is added once the other Part A ingredients are mixed and heated. Once the Ceteareth-25 is dissolved, the Stearic Acid is added. Part B is prepared by dissolving the Triclosan in 1,2 Propylene Glycol. Water which has evaporated is added. Slowly under mixing, Part B is poured into part A. To stock, a plastic bag into the bucket is put in to be sealed after cooling. Moulds was filled at about 70° C.

Example 20

Anti-Perspirant Stick

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 29 deodorant composition Ingredient Amount (wt %) Cyclomethicone¹⁾ (Part A) 55.56 Stearyl Alcohol²⁾ (Part A) 21.21 PPG-14 Butyl ether³⁾ (Part A) 2.02 Hydrogenated Castor Oil⁴⁾ (Part A) 1.01 Aluminium Zirconium tetrachlorohydrex- 20.20 Gly⁵⁾ (Part B) ¹⁾Dow Corning ® 345 Fluid; trademark and origin: Dow Corning ²⁾Lanette ® 18; trademark and origin: BASF ³⁾Tegosoft ® PBE; trademark and origin: Evonik ⁴⁾Cutina ® HR; trademark and origin: BASF ⁵⁾Summit AZP-908; trademark and origin: Reheis All the components of Part A are weighted, heated up to 70-75° C. and mixed well. Ingredient of Part B is dispersed in Part A. The mixture is mixed and putted into a tick at 65° C.

Example 21

Day Cream

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 30 day cream Ingredients % ARLATONE 985 5.000 Ethoxylated Fatty Alcohol Ester CETYL ALCOHOL 0.500 TEFOSE 2561 4.000 Ceteth-20 (and) Glyceryl Stearate (and) PEG-6 Stearate (and) Steareth-20 COSBIOL 1.000 Squalan MINERAL OIL 30-40 cp 2.000 Paraffin Oil PETROLEUM JELLY 6.000 Petrolatum WATER deionized 75.850 PROPYLENE GLYCOL 5.000 GLYDANT PLUS 0.150 DMDM Hydantoin (and) Iodopropynyl Butylcarbamate PNC 400 0.200 Sodium Carbomer PERFUME 0.300 Total 100.00

Example 22

Talc Formulation

A sufficient amount of granules 1-5 is weighed and mixed in introduced in a standard talc base: 100% talc, very slight characteristic odor, white powder, origin: LUZENAC to add the equivalent of 0.2% perfume.

Example 23

Shower-Gel Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 31 shower gel composition Ingredients Amount (% wt) Function WATER deionised 49.350 Solvent Tetrasodium EDTA ¹⁾ 0.050 Chelating agent Acrylates Copolymer²⁾ 6.000 Thickener Sodium C12-C15 Pareth Sulfate ³⁾ 35.000 Surfactant Sodium Hydroxide 20% aqueous 1.000 pH adjuster solution Cocamidopropyl Betaine⁴⁾ 8.000 Surfactant Methylchloroisothiazolinone and 0.100 Preservative Methylisothiazolinone⁵⁾ Citric Acid (40%) 0.500 pH adjuster ¹⁾ EDETA B POWDER; trademark and origin: BASF ²⁾CARBOPOL AQUA SF-1 POLYMER; trademark and origin: NOVEON ³⁾ ZETESOL AO 328 U; trademark and origin: ZSCHIMMER & SCHWARZ ⁴⁾TEGO-BETAIN F 50; trademark and origin: GOLDSCHMIDT ⁵⁾KATHON CG; trademark and origin: ROHM & HASS Ingredients are mixed, pH is adjusted to 6-6.3 (Viscosity: 4500cPo+/−1500cPo (Brookfield RV/Spindle #4/20 RPM)).

Example 24

Shower-Gel Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 32 shower gel composition Ingredients Amount (% wt) Function WATER deionized 52.40 Solvent Tetrasodium EDTA ¹⁾ 0.10 Chelating agent Sodium Benzoate 0.50 Preservative Propylene Glycol 2.00 Solvent Sodium C12-C15 Pareth Sulfate ²⁾ 35.00 Surfactant Cocamidopropyl Betaine³⁾ 8.00 Surfactant Polyquaternium-7⁴⁾ 0.20 Conditioning agent Citric Acid (40%) 1.00 pH adjuster Sodium Chloride 0.80 Viscosity adjuster ¹⁾ EDETA B POWDER; trademark and origin: BASF ²⁾ ZETESOL AO 328 U; trademark and origin: ZSCHIMMER & SCHWARZ ³⁾TEGO-BETAIN F 50; trademark and origin: GOLDSCHMIDT ⁴⁾MERQUAT 550; trademark and origin: LUBRIZOL Ingredients are mixed, pH is adjusted to 4.5 (Viscosity: 3000cPo+/−1500cPo (Brookfield RV/Spindle #4/20 RPM)).

Example 25

Shower-Gel Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 33 shower gel composition Ingredients Amount (% wt) Function WATER deionized 50.950 Solvent Tetrasodium EDTA ¹⁾ 0.050 Chelating agent Sodium Benzoate 0.50 Preservative Glycerin 86% 3.50 Solvent Sodium Laureth Sulfate ²⁾ 27.0 Surfactant Polyquaternium-7³⁾ 1.0 Conditioning Agent Coco-Betaine⁴⁾ 6.0 Surfactant PEG-120 Methyl Glucose 1.0 Thickener trioleate⁵⁾ Citric Acid (40%) 1.0 pH adjuster Glycol Distearate & Laureth-4 & 3.0 Pearlizing agent Cocamidopropyl Betaine⁶⁾ Sodium Chloride 20% 5.0 Viscosity adjuster PEG-40 Hydrogenated Castor Oil⁷⁾ 1.0 Viscosity adjuster ¹⁾ EDETA B POWDER; trademark and origin: BASF ²⁾ Texapon NSO IS; trademark and origin: COGNIS ³⁾MERQUAT 550; trademark and origin: LUBRIZOL ⁴⁾DEHYTON AB-30; trademark and origin: COGNIS ⁵⁾GLUCAMATE LT; trademark and origin: LUBRIZOL ⁶⁾EUPERLAN PK 3000 AM; trademark and origin: COGNIS ⁷⁾CREMOPHOR RH 40; trademark and origin: BASF Ingredients are mixed, pH is adjusted to 4.5 (Viscosity: 4000cPo+/−1500cPo (Brookfield RV/Spindle #4/20 RPM))

Example 26

Hair Coloration Composition

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed with alkaline base A to add the equivalent of 0.2% perfume. 2 g of alkaline base A is then mixed with 2 g of the oxidative base B

TABLE 34 Composition of the alkaline base A Ingredients % Phase A Water 39.13 Carbomer ¹⁾ 0.9 p-phenylenediamine ²⁾ 1 m-aminophenol ³⁾ 1 m-phenylenediamine sulfate ⁴⁾ 0.07 resorcinol ⁵⁾ 0.5 Phase B Propylene glycol 6 Laureth-2 ⁶⁾ 6 Laureth-12 ⁷⁾ 6 Dimethicone ⁸⁾ 0.7 Phase C Cetearyl alcohol ⁹⁾ 18 Oleth-30 ¹⁰⁾ 3 Lauric acid 3 Glycol distearate ¹¹⁾ 3 Phase D Sodium metabisulfite ¹²⁾ 0.4 Silica dimethyl silyate 0.3 Pentasodium pentetate ¹³⁾ 0.2 Polyquaternium-22 ¹⁴⁾ 1 Ammonium Hydroxide ¹⁵⁾ 9.3 Perfume 0.5 ¹⁾ Carbopol Ultrez 10 Polymer ²⁾ Covastyle PAP ³⁾ Covastyle MAP ⁴⁾ Covastyle MPDS ⁵⁾ Resorcine ⁶⁾ Lipocol L 12 ⁷⁾ Arlypon F ⁸⁾ Dow Corning 200 Fluid 350 ⁹⁾ Lanette O ¹⁰⁾ Eumulgin O 30 ¹¹⁾ Cutina AGS ¹²⁾ Covastyle MBS ¹³⁾ Dissolvine D-40 ¹⁴⁾ Merquat 280 ¹⁵⁾ Ammonium hydroxide 30% aqueous solution

Procedure:

All ingredients of Phase A were mixed and heated until 75° C. All ingredients of Phase B were combined and melt at 70-75° C. Phase B was added to Phase A (both at 70-75° C.) with good agitation. Phase C was added while mixing continued until cooled down to room temperature At room temperature Phase D ingredients were added while mixing Remaining ingredients of Phase C were added under stirring.

TABLE 35 Composition of the oxidative base B Ingredients % Phase A Water 75 Phase B Cetearyl alcohol and dicethyl phospahate and 3.5 Cteteth-20 phosphate ¹⁾ Mineral oil ²⁾ 3.5 Cetyl acetate and acetylated lanolin alcohol ³⁾ 0.35 Steareth-20 ⁴⁾ 0.35 Phase C Hydrogen peroxide ⁵⁾ 17 Perfume 0.3 ¹⁾ Crodafos CS 20 Acid ²⁾ Paraffin Oil 30-40 cPs ³⁾ Acetulan ⁴⁾ Brij 78P ⁵⁾ Hydrogen Peroxide 35% aqueous solution

Procedure:

All ingredients of Phase A were mixed and heated until 75° C. All ingredients of Phase B were combined and melt at 70-75° C. Phase B was added to Phase A (both at 70-75° C.) with good agitation and mixing continued until cooled down to room temperature At room temperature Phase C ingredients were added while mixing

Example 27

Hand Dishwash

A sufficient amount of microcapsule slurry microcapsule slurry A-D is weighed and mixed in the following composition to add the equivalent of 0.2% perfume.

TABLE 36 Hand dishwash composition Ingredients Amount (% wt) Function Linear alkylbenzene sulfonic 20 Anionic surfactant acid ⁽¹⁾ Diethanolamide ⁽²⁾ 3.5 Foam booster Sodium Hydroxide (50%) ⁽³⁾ 3.4 pH Adjuster/neutralizer Secondary alcohol 2.5 Non-ionic surfactant ethoxolate ⁽⁴⁾ Sodium xylene sulfonate 6.3 Hydrotrope Water 64.3 Solvent ⁽¹⁾ Biosoft S-118 ®; trademark and origin: Stepan Company ⁽²⁾ Ninol 40-CO ®; trademark and origin: Stepan Company ⁽³⁾ Stepanate SXS ®; trademark and origin: Stepan Company ⁽⁴⁾ Tergitol 15-S-9 ®; trademark and origin: Dow Chemical Company Water with sodium hydroxide and diethanolamide are mixed. LAS is added. After the LAS is neutralized, the remaining ingredients are added. The pH was Checked (=7-8) and adjusted if necessary.

Example 28

Toothpaste Formulation

A sufficient amount of microcapsule slurry R (corresponding to microcapsules microcapsule slurry A-D except that a flavor is encapsulated instead of a perfume) is weighed and mixed in the following composition to add the equivalent of 0.2% flavor.

TABLE 37 Toothpaste formulation Ingredients Amount (% wt) Polyethylene glycol 400  2.0% Xanthan Gum 0.60% Sorbitol 70% Solution 50.0% Sodium Fluoride 0.220%  Sodium Benzoate 0.20% Water 15.230%  Hydrated Silica¹⁾ 22.0% Hydrated Silica²⁾  7.0% Titanium Dioxide CI77891 0.500%  Sodium Lauryl Sulfate 1.250%  Flavor 1.20% TOTAL  100% ¹⁾Tixosil 73; trademark and origin: ²⁾Tixosil 43; trademark and origin:

Example 29

Dicalcium Phosphate Based Toothpaste Formulation

A sufficient amount of microcapsule slurry R (corresponding to microcapsules microcapsule slurry A-D except that a flavor is encapsulated instead of a perfume) is weighed and mixed in the following composition to add the equivalent of 0.2% flavor.

TABLE 38 Toothpaste formulation Ingredients Amount (% wt) Sodium carboxymethyl cellulose 1.20% Flavor 1.20% DI/Purified Water Q.S to Final Wt. Sodium Lauryl Sulfate 1.30% Glycerine 20.0% Sodium Saccharin 0.20% Dicalcium phosphate dihydrate 36.0% Methylparaben 0.200%  Silica¹⁾  3.0% TOTAL  100% ¹⁾Aerosil ®200; trademark and origin:

Example 30

Mouthwash Alcohol Free Formulation

A sufficient amount of microcapsule slurry R (corresponding to microcapsules microcapsule slurry A-D except that a flavor is encapsulated instead of a perfume) is weighed and mixed in the following composition to add the equivalent of 0.2% flavor.

TABLE 39 Mouthwash formulation Ingredients Amount (% wt) Propylene Glycol  10.0% Flavor 0.240% DI/Purified Water Q.S to Final Wt. Poloxamer 407 NF 0.240% Sodium Lauryl Sulfate 0.040% Sorbitol 70% Solution  10.0% Sodium Saccharin 0.030% Glycerine  3.0% Sodium Benzoate  0.10% Sucralose 0.020% Benzoic Acid 0.050% TOTAL  100%

Example 31

Mouthwash Formulation

A sufficient amount of microcapsule slurry R (corresponding to microcapsules microcapsule slurry A-D except that a flavor is encapsulated instead of a perfume) is weighed and mixed in the following composition to add the equivalent of 0.2% flavor.

TABLE 40 Mouthwash formulation Ingredients Amount (% wt) Ethyl Alcohol 190 Proof 15.00%  Flavor 0.24% DI/Purified Water Q.S to Final Wt. Poloxamer 407 NF 0.24% Sodium Lauryl Sulfate 0.04% Sorbitol 70% Solution 10.00%  Sodium Saccharin 0.03% Glycerine 3.00% Sodium Benzoate 0.10% Sucralose 0.02% Benzoic Acid 0.05% TOTAL  100% 

1. A delivery system comprising a biodegradable carrier and a perfume formulation, wherein the carrier has a biodegradability of at least 60% within 60 days according to OECD301F.
 2. The delivery system according to claim 1, wherein the perfume formulation comprises 0 to 60 wt. % of a hydrophobic solvent, based on the total weight of the perfume formulation, 40 to 100 wt. % of a perfume oil, on the total weight of the perfume formulation, and optionally, other active ingredients.
 3. The delivery system according to claim 1, wherein the perfume formulation comprises a perfume oil which has at least two of characteristics including: at least 35% of perfuming ingredients having a log P above 3, at least 20% of Bulky materials including one or more of: perfuming ingredients comprising a cyclohexane, cyclohexene, cyclohexanone, or cyclohexenone ring substituted with at least 1 to 4 nodes comprising substituent, perfuming ingredients comprising a cyclopentane, cyclopentene, cyclopentanone, or cyclopentenone ring substituted with 4 or more nodes comprising substituent, perfuming ingredients comprising a phenyl ring or perfuming ingredients comprising a cyclohexane, cyclohexene, cyclohexanone, or cyclohexenone ring substituted with 5 or more nodes comprising substituent, perfuming ingredients comprising at least two fused or linked 5 membered or 6 membered rings, perfuming ingredients comprising a camphor-like ring structure, or perfuming ingredients comprising at least one 7 to 20 membered ring; and at least 15% of high impact perfume materials having a Log T<−4.
 4. The delivery system according to claim 3, wherein the perfume oil has all of the characteristics.
 5. The delivery system according to claim 2, wherein the perfume oil and the hydrophobic solvent have at least two Hansen solubility parameters selected from a first group consisting of: an atomic dispersion force (δD) from 12 to 20, a dipole moment (δP) from 1 to 8, and a hydrogen bonding (δH) from 2.5 to
 11. 6. The delivery system according to claim 5, wherein the perfume oil and the hydrophobic solvent have at least two Hansen solubility parameters selected from a second group consisting of: an atomic dispersion force (δD) from 14 to 20, a dipole moment (δP) from 1 to 7, and a hydrogen bonding (δH) from 4 to
 11. 7. The delivery system according to claim 1, wherein the biodegradable carrier is a biodegradable shell or a biodegradable polymeric carrier matrix.
 8. The delivery system according to claim 1, wherein the delivery system has a biodegradability of at least 40% within 60 days according to OECD301F.
 9. Perfuming composition comprising: a delivery system according to claim 1, and optionally, a free perfume oil.
 10. The perfuming composition according to claim 9, wherein the total amount of the delivery system is 0.05 to 5 wt. % based on the total perfuming composition, and the total amount of the free perfume oil is 0.05 to 5 wt. % based on the total perfuming composition.
 11. The perfuming composition according to claim 9, wherein a total perfume oil of the perfume formulation entrapped in the delivery system and total free perfume oil are present in the perfuming composition in a weight ratio of 1:20 to 20:1.
 12. Perfumed consumer product comprising the delivery system according to claim
 1. 13. The consumer product according to claim 12, wherein the perfumed consumer product is a fine perfume, a splash or eau de perfume, a cologne, a shave or after-shave lotion, a liquid or solid detergent, a mono or multi chamber unidose detergent, a fabric softener, a fabric refresher, liquid or solid scent-boosters, a dryer sheet, an ironing water, a paper, a bleach, a carpet cleaners, curtain-care products, a shampoo, a coloring preparation, a color care product, a hair shaping product, a dental care product, a disinfectant, an intimate care product, a hair spray, a hair conditioning product, a vanishing cream, a deodorant or antiperspirant, hair remover, tanning or sun product, nail products, skin cleansing, a makeup, a perfumed soap, shower or bath mousse, oil or gel, or a foot/hand care products, a hygiene product, an air freshener, a “ready to use” powdered air freshener, a mold remover, furnisher care, wipe, a dish detergent or hard-surface detergent, a leather care product, or a car care product.
 14. The perfumed consumer product according to claim 12, wherein the perfumed consumer product is a liquid or solid detergent, a mono or multi chamber unidose detergent, a fabric softener, liquid or solid scent-boosters, a dryer sheet, a shampoo, a shower gel, a hair conditioning product, or a deodorant or antiperspirant.
 15. The delivery system according to claim 1, wherein the carrier has a biodegradability of at least 80% within 60 days.
 16. The delivery system according to claim 9, wherein the biodegradable carrier is a biodegradable shell.
 17. The perfuming composition according to claim 11, wherein the total perfume oil of the perfume formulation entrapped in the delivery system and total free perfume oil are present in the perfuming composition in a weight ratio of 10:1 to 1:10.
 18. Perfumed consumer product comprising the perfuming composition according to claim
 9. 